首页|混凝沉淀工艺对微塑料的去除性能和机理研究

混凝沉淀工艺对微塑料的去除性能和机理研究

扫码查看
为考察混凝沉淀工艺对水中微塑料的去除性能,试验选取了亲水性的聚对苯二甲酸乙二醇酯(PET)和疏水性的聚氯乙烯(PVC)为研究对象,通过混凝烧杯试验,探究了聚合氯化铝(PAC)、硫酸铝、硫酸铁3种混凝剂对微塑料的去除效果,考察了 pH、原水浊度、粒径大小、塑料老化等因素对微塑料去除的影响并分析了其机理。结果表明,聚合氯化铝对PET和PVC的去除效果最好,在原水中微塑料初始浓度为1。61×104个/L时,最高去除率可分别达到52。59%和49。07%,电中和是水中微塑料去除的主导机制,pH=7。0时微塑料去除率为51。70%,原水浊度增加能够促进微塑料的去除效率,对于密度大于水的微塑料,粒径越大去除效果越好,混凝沉淀对老化微塑料的去除效果优于原始微塑料。
Removal Performance and Mechanism of Microplastics by Coagulation-Sedimentation Process
The removal performance of microplastics(MPs)in water by coagulation-sedimentation process was examined,employing hydrophilic polyethylene terephthalate(PET)and hydrophobic polyvinyl chloride(PVC)as the prototypes of microplastics.The removal efficiency of MPs by polyaluminum chloride(PAC),aluminum sulfate,iron sulfate was explored,the effects of pH,raw water turbidity,particle size and aging on MPs removal were investigated.The removal mechanism was analyzed.The results showed polyaluminum chloride has the best removal on PET and PVC,and the highest removal rate can reach 52.59%and 49.07%when the initial level of microplastics in water was 1.61×104 pcs/L.Charge neutralization was identi-fied as the dominant mechanism for microplastic removal.The removal rates of microplastics reached 51.70%at pH=7.0 and the increase of raw water turbidity promoted the removal efficiency of microplastics.for microplastics with a density greater than water,the larger the particle size,the better the removal efficiency.The aged microplastics were readily removed than raw microplastics.

coagulation-sedimentationmicroplasticscharge neutralizationaged microplastics

仇付国、王顺喜、梁安棋、夏鑫、付昆明

展开 >

北京建筑大学城市雨水系统与水环境教育部重点实验室,北京 100044

混凝沉淀 微塑料 电中和 老化微塑料

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(4)