环境科学与技术2024,Vol.47Issue(4) :87-96.DOI:10.19672/j.cnki.1003-6504.0100.24.338

粉煤灰制备沸石分子筛及其吸附脱除氨氮性能

Preparation of Zeolite Molecular Sieve with Fly-ash and Its Application in Adsorbing and Removing Ammonia Nitrogen

刘欣蕾 龚禄稍 邵艳祥 郑易帆 杨雨萌 朱本峰 卫国英
环境科学与技术2024,Vol.47Issue(4) :87-96.DOI:10.19672/j.cnki.1003-6504.0100.24.338

粉煤灰制备沸石分子筛及其吸附脱除氨氮性能

Preparation of Zeolite Molecular Sieve with Fly-ash and Its Application in Adsorbing and Removing Ammonia Nitrogen

刘欣蕾 1龚禄稍 1邵艳祥 1郑易帆 1杨雨萌 1朱本峰 1卫国英1
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作者信息

  • 1. 中国计量大学材料与化学学院,浙江 杭州 310018
  • 折叠

摘要

当前大量含氮废水的排入不仅使湖泊水体富营养化加剧,更对各类生物的生存和健康造成了很大威胁.由于沸石分子筛具有良好的吸附选择性和离子交换性,可以用来吸附脱除水中的氨氮,因此成为当前研究的热点.文章以粉煤灰为主要原料,采用碱熔融-水热法制备Na-X型沸石分子筛,通过正交试验得到沸石分子筛的最佳制备工艺条件,探索了氨氮溶液初始浓度、pH值、吸附时间、吸附温度以及阳离子对沸石分子筛吸附氨氮性能的影响.结果表明:Na-X型分子筛的最佳饱和氨氮吸附率为74.89%;Na-X型沸石分子筛吸附过程符合准二级动力学模型,吸附等温线符合Freundlich模型;其氨氮吸附量与初始浓度和吸附时间呈正相关,与温度呈负相关;强酸或强碱环境会使分子筛吸附性能下降.Na-X型分子筛氨氮吸附率较高、可多次循环使用,在废水治理方面有着广泛的应用前景.

Abstract

Presently,the emission of a large amount of nitrogen-containing wastewater into lakes not only aggravates lake eutrophication,but also poses severe threats to the health and survival of various species of organism.This article refers to a kind of zeolite molecular sieves that can be used to adsorb and remove ammonia nitrogen(NH3-N)from water due to the good adsorption selectivity and ion exchange.A laboratory experiment was performed with the fly-ash sampled collected from a thermo-power plant as main raw material to prepare Na-X zeolite by alkali melting-hydrothermal method,and the orthogonal experiment was conducted to determine the optimal preparation process condition.The experiment of NH3-N adsorption was thereby conducted probing into the effect of the initial NH3-N concentration,pH,adsorption time,adsorption temperature and cations on the adsorption of NH3-N by the zeolite.It was showed that the best saturated NH3-N adsorption rate of Na-X zeolite reached 74.89%,and the process of NH3-N adsorption onto Na-X zeolite fit the quasi-second-order kinetic model,and the adsorption isotherm conformed to the Freundlich model,NH3-N adsorption capacity being positively correlated with the initial NH3-N concentration and adsorption time,and negatively correlated with temperature.To sum up,the Na-X typed molecular sieve features rather high NH3-N adsorption rate,and could be recycled a number of times,so it has wide appli-cations in wastewater treatment.

关键词

粉煤灰/沸石分子筛/碱熔融水热法/氨氮吸附

Key words

fly ash/zeolite/alkali melting hydrothermal method/ammonia nitrogen adsorption

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基金项目

国家自然科学基金(52001300)

国家自然科学基金(52171083)

出版年

2024
环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
参考文献量3
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