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潟湖污泥改性土工程特性与环境风险研究

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为实现典型潟湖污泥的无害化处理与资源化利用,文章以海南万宁市小海潟湖污泥为研究对象,利用高炉矿渣、钢渣、工业石膏等大宗工业固废为原料制备的软土固化剂对污泥土进行固化处理。结果显示,软土固化剂改善了潟湖污泥的抗压强度、抗剪强度以及液塑限等工程性能,降低了污泥土中的重金属浸出浓度与迁移释放能力,同时增加了种子发芽指数,使改性污泥土能够满足建设用地回填土强度要求与园林绿化用土的安全指标。通过SEM、XRD表征分析发现,潟湖污泥原样中的硅、铝成分,在碱性激发剂、钢渣粉、矿粉等提供的碱性环境下参与了水化反应,使改性污泥土表面出现大量孔洞以及棒状、片状等稳定的结晶物和以凝胶态存在的水化产物,进一步使污泥土内部结构密实紧凑,颗粒间联结增强。经过软土固化剂固化后的潟湖污泥土工程特性得到显著提升,并使污泥中重金属得到固化稳定化,其环境生态毒害性也得到有效减弱。
Study on Engineering Characteristics and Environmental Risks of Lagoon Sludge Modified Soil
In order to achieve the harmless treatment and resource utilization of typical lagoon sludge,the sludge from Xiaohai Lagoon in Wanning City,Hainan Province was selected as the research subject.A soft soil curing agent,prepared from bulk industrial solid wastes such as blast furnace slag,steel slag,and industrial gypsum,was employed for sludge stabi-lization.The results demonstrated that the soft soil hardening agent enhanced the compressive strength,shear strength,and liquid-plastic limit of lagoon sludge while reducing leaching concentrations of heavy metals and their migration/release capacity.Additionally,it improved seed germination index to meet construction land backfill strength requirements and safety standards for garden greening soil.SEM and XRD analysis revealed that silicon and aluminum components in original lagoon sludge participated in hydration reactions under an alkaline environment provided by alkaline activators,steel slag powder and mineral powders.This resulted in numerous holes on the modified sludge surface along with stable crystallites(such as rods,flakes)and hydrated gel state products within a compacted internal structure with en-hanced intergranular connections.Consequently,engineering characteristics of lagoon sludge significantly improved af-ter being treated with a soft soil curing agent while effectively solidifying/stabilizing heavy metals present in the sludge to mitigate environmental/ecological toxicity.

lagoon sludgesoft soil curing agentcuring modificationlandfill soilengineering characterizationenviron-mental risk

王富睿、杜征宇、罗腾、王龙、陈永修、姚秋艳、廖爱浦、刘悦、侯浩波、曾天宇

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中国电力工程顾问集团中南电力设计院有限公司,湖北 武汉 430071

武汉大学(肇庆)资源与环境技术研究院,广东 肇庆 526238

潟湖污泥 软土固化剂 固化改性 填埋土 工程特性分析 环境风险

中国电力工程顾问集团中南电力设计院有限公司科技项目

40-1A-KY202054-S101

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(5)