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路边土壤重金属锌的污染源解析

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随着公路建设步伐的加快和汽车保有量的增加,公路交通源是除工业污染源外土壤重金属污染物的主要排放源之一,已对路边土壤造成不同程度的污染,其中重金属锌(Zn)为主要污染元素之一。以往的研究多侧重于路边土壤重金属Zn的污染特征、分布规律及定性来源的分析等方面,对路边土壤中重金属Zn的定量解析尚缺系统分析。该研究以路边土壤、大气和路面沉积物为研究对象,利用电感耦合等离子体质谱仪(ICP-MS)测定路边大气降尘、路面沉积物、汽车轮胎以及路边土壤中Zn同位素值,采用同位素示踪法定量分析路边土壤中Zn污染来源及相对贡献率。结果表明:汽车轮胎的磨损对路边土壤Zn的贡献最大,其次是路面沉积物,最后是路边大气降尘。其中,非工业区轮胎磨损、路面沉积物和大气降尘分别对路边土壤中Zn的贡献率为71%~77%、12%~18%和10%~11%;工业区轮胎磨损、路面沉积物和大气降尘对路边土壤中Zn的贡献率为65%~70%、19%~24%和10%~12%。研究结果可为路边土壤重金属Zn污染的预防与防治提供依据。
Sources Apportionment of Roadside Soil Pollution of Heavy Metal Zinc
With the acceleration of highway construction and growing retain number of vehicles,the road traffic pollution besides industrial pollution is one of the main sources of heavy-metal pollution in soil,especially heavy-metal pollution to roadside soil,and among others,zinc(Zn)is one of the main heavy-metal pollutants.Previous studies mostly focused on the pollution characteristics,distribution rules and qualitative sources of Zn in roadside soil,but systematic analysis of the quanti-tative analysis is not enough,so it is difficult to provide effective support for the prevention and control of roadside soil heavy-metal pollution.In this study,with roadside soil,atmosphere dust-fall and pavement sediments being taken as the research objects,the values of Zn isotopes in roadside atmospheric dust-fall,pavement sediments,automobile tires and roadside soil were determined by using ICP-MS,and the sources of Zn pollution to roadside soil,and their contribution rate were quan-titatively analyzed by isotope tracer method.Consequently,it was showed that the wear of automobile tires contributed the greatest Zn pollution to the roadside soil,followed by the road sediments and the roadside atmospheric dust,and specifical-ly,in non-industrial areas the contribution of tires wear was in the range of 71%~77%,road sediments 12%~18%and atmo-spheric dustfall 10%~1 1%,while in industrial areas,the contribution of tire wear in the range of 65%~70%,road sediment 19%~24%and atmospheric dust-fall 10%~12%.It is expected that the result of the study could provide a basis for the pre-vention and control of Zn pollution in roadside soil.

roadside soilroadside atmospheric dustfallroad sedimentsautomobile tiressource apportionment

徐贝贝、杨宇、任志建、李康建、余爱华

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南京林业大学土木工程学院,江苏 南京 210037

路边土壤 路边大气降尘 路面沉积物 汽车轮胎 源解析

国家科技支撑计划课题2021江苏省大学生实践创新训练计划项目

2015BAD07B0103202110298080Y

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(6)