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氧化石墨烯界面调控纳滤膜制备及性能研究

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为提高传统聚酰胺纳滤膜渗透性能和抗污染性能,文章以聚砜(PSF)超滤膜为基材,以哌嗪、均苯三甲酰氯为水相和有机相单体,引入氧化石墨烯(GO)作为亲水改性材料,通过界面聚合法制备氧化石墨烯复合纳滤膜(GO-PA-PSF膜),研究GO占比对膜表面形貌、化学结构及分离性能的影响。结果表明,当GO质量分数为0。01%时,GO-PA-PSF膜表面开始出现褶皱,膜表面粗糙度、亲水性和负电性增强,其渗透通量为50。47 L/(m2·h),对Na2SO4的截留率为98。14%,在30 h脱盐试验中保持良好的稳定性,对3种模型污染物的抗污染性能有所提升。
Research on Graphene-Oxide Interfacial Modulated Nanofiltration Membranes:Preparation and Performance
To upgrade the permeability and anti-fouling performance of conventional polyamide nano-filtration membranes,a laboratory experiment was concucted to fabricate the graphene oxide composite nano-filtration membrane(GO-PA-PSF)using the inter-facial polymerization method,which involved polysulfone(PSF)ultra-filtration membranes used as the substrate,piperazine and homotrimethylene tricarbonyl chloride as the aqueous-phase and organic-phase monomers,and graphene oxide(GO)as the hydrophilic modified material;and then the effect of the propertion of GO on membrane surface morphology,chemical structure and separation performance was investigated.Consequently,it was showed that as GO mass fraction came to 0.01%,the surface of GO-PA-PSF membrane began to wrinkle,increasing membrane surface roughness,hydrophilicity and negative electro-negativity,the permeation flux was 50.47 L/(m2·h),Na2SO4 retention rate 98.14%;in addition,the GO-PA-PSF desalination test maintained stable quite well in the 30 h,demonstrating a better anti-fouling performance in the treatment of three specific pollutants.

graphene oxideinterface polymerizationpolyamide nano-filtration membraneanti-fouling performance

丰桂珍、方圳生、胡小杰、张火梅、陈俊

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华东交通大学土木建筑学院,江西 南昌 330013

氧化石墨烯 界面聚合 聚酰胺纳滤膜 抗污染性能

国家自然科学基金项目

51858019

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(8)