环境科学与技术2024,Vol.47Issue(8) :17-25.DOI:10.19672/j.cnki.1003-6504.0534.24.338

氧化石墨烯界面调控纳滤膜制备及性能研究

Research on Graphene-Oxide Interfacial Modulated Nanofiltration Membranes:Preparation and Performance

丰桂珍 方圳生 胡小杰 张火梅 陈俊
环境科学与技术2024,Vol.47Issue(8) :17-25.DOI:10.19672/j.cnki.1003-6504.0534.24.338

氧化石墨烯界面调控纳滤膜制备及性能研究

Research on Graphene-Oxide Interfacial Modulated Nanofiltration Membranes:Preparation and Performance

丰桂珍 1方圳生 1胡小杰 1张火梅 1陈俊1
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作者信息

  • 1. 华东交通大学土木建筑学院,江西 南昌 330013
  • 折叠

摘要

为提高传统聚酰胺纳滤膜渗透性能和抗污染性能,文章以聚砜(PSF)超滤膜为基材,以哌嗪、均苯三甲酰氯为水相和有机相单体,引入氧化石墨烯(GO)作为亲水改性材料,通过界面聚合法制备氧化石墨烯复合纳滤膜(GO-PA-PSF膜),研究GO占比对膜表面形貌、化学结构及分离性能的影响.结果表明,当GO质量分数为0.01%时,GO-PA-PSF膜表面开始出现褶皱,膜表面粗糙度、亲水性和负电性增强,其渗透通量为50.47 L/(m2·h),对Na2SO4的截留率为98.14%,在30 h脱盐试验中保持良好的稳定性,对3种模型污染物的抗污染性能有所提升.

Abstract

To upgrade the permeability and anti-fouling performance of conventional polyamide nano-filtration membranes,a laboratory experiment was concucted to fabricate the graphene oxide composite nano-filtration membrane(GO-PA-PSF)using the inter-facial polymerization method,which involved polysulfone(PSF)ultra-filtration membranes used as the substrate,piperazine and homotrimethylene tricarbonyl chloride as the aqueous-phase and organic-phase monomers,and graphene oxide(GO)as the hydrophilic modified material;and then the effect of the propertion of GO on membrane surface morphology,chemical structure and separation performance was investigated.Consequently,it was showed that as GO mass fraction came to 0.01%,the surface of GO-PA-PSF membrane began to wrinkle,increasing membrane surface roughness,hydrophilicity and negative electro-negativity,the permeation flux was 50.47 L/(m2·h),Na2SO4 retention rate 98.14%;in addition,the GO-PA-PSF desalination test maintained stable quite well in the 30 h,demonstrating a better anti-fouling performance in the treatment of three specific pollutants.

关键词

氧化石墨烯/界面聚合/聚酰胺纳滤膜/抗污染性能

Key words

graphene oxide/interface polymerization/polyamide nano-filtration membrane/anti-fouling performance

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基金项目

国家自然科学基金项目(51858019)

出版年

2024
环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
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