首页|金矿区周边桃园地土壤重金属赋存特征、生物有效性及来源分析

金矿区周边桃园地土壤重金属赋存特征、生物有效性及来源分析

扫码查看
文章以北京市平谷万庄金矿区周边桃园地土壤为研究对象,运用地统计学、风险评价编码法(RAC)、次生相与原生相分布比值法(RSP)、主成分分析法(PCA)及聚类分析法分析了重金属的含量、形态特征、生物有效性及重金属元素的主要来源。结果表明:土壤中As、Cd和Pb等3项重金属在土壤中呈现相对明显的累积;土壤中As、Cr、Hg、Pb和Zn等5项重金属以残渣态为主要形态,而Cd以离子交换态和残渣态为主要形态;土壤重金属元素RAC风险评价的污染程度大小排序为:Cd>Zn>Hg>Cr=Pb>As,土壤中Cd元素RSP主要为中、重度污染;主成分和聚类分析结果表明:自然源和人为源的混合源(As、Cd和Pb)贡献率为44。235%,农业生产源(Cu和Zn)和大气沉降源(Hg)贡献率为21。428%,自然源(Cr和Ni)贡献率为14。338%。
Characteristics,Bioefficacy and Source Analysis of Heavy Metals in Peach Orchard Soils Around the Gold Mining Area
The content of heavy metals,morphological characteristics,bioeffectiveness and the main sources of heavy metal elements were analysed by using geostatistics,Risk Assessment Coding(RAC),Ratio of Distribution of Secondary and Prima-ry Phases(RSP),Principal Component Analysis(PCA)and Cluster Analysis in the soils of peach orchard land around the gold mining area of Wanzhuang,Pinggu,Beijing,China.The results showed that three heavy metals,As,Cd and Pb,showed relatively obvious accumulation in the soil;five heavy metals in the soil,including As,Cr,Hg,Pb and Zn,were in the main form of residue state,while Cd was in the main form of ion-exchange state and residue state;the order of the pollution degree of the risk evaluation of the RAC of soil heavy metal elements was as Cd>Zn>Hg>Cr=Pb>As,and the RSP of Cd was mainly medium and heavy.The RSP of Cd element in soil is mainly medium and heavy pollution.The results of principal component and cluster analysis showed that the contribution of mixed natural and anthropogenic sources(As,Cd and Pb)was 44.235%,agricultural production sources(Cu and Zn)and atmospheric deposition sources(Hg)were 21.428%,and natural sources(Cr and Ni)were 14.338%.

soilheavy metalschemical formbioeffectivenessassessmentanalysis of sources

邓凯文、安永龙、黄勇

展开 >

北京市生态地质研究所,北京 100120

土壤 重金属 化学形态 生物有效性 评价 来源分析

北京市政府公益性项目

11000022T000000439575

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(9)