环境科学与技术2024,Vol.47Issue(11) :106-117.DOI:10.19672/j.cnki.1003-6504.1384.24.338

李家河库区及入库河流水化学组成和溶解性有机物荧光特征

Hydro-chemical Composition and Fluorescence Characteristics of Dissolved Organic Matter in Lijiahe Reservoir Area and Its Inflow Streams

马语晗 胡恩 赵丹 胡龙刚 王浩 李明
环境科学与技术2024,Vol.47Issue(11) :106-117.DOI:10.19672/j.cnki.1003-6504.1384.24.338

李家河库区及入库河流水化学组成和溶解性有机物荧光特征

Hydro-chemical Composition and Fluorescence Characteristics of Dissolved Organic Matter in Lijiahe Reservoir Area and Its Inflow Streams

马语晗 1胡恩 2赵丹 2胡龙刚 2王浩 3李明1
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作者信息

  • 1. 西北农林科技大学资源环境学院,陕西 杨凌 712100
  • 2. 陕西省环境科学研究院,陕西 西安 710061
  • 3. 西北农林科技大学水土保持科学与工程学院,陕西 杨凌 712100
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摘要

水库作为重要供水水源地,可能面临富营养化、耗氧有机物污染等水质问题,对库区水体进行污染物源解析是实现精准治污、科学管理的重要依据.该研究通过水化学组成分析、三维荧光光谱结合平行因子分析法以及硝酸盐氮氧同位素指标等方法,并采用贝叶斯混合模型对溶解性有机物(DOM)和硝酸盐进行溯源分析.结果表明,枯水期水库水体荧光指数(FI)均高于丰水期,且枯水期水库上游河流DOM的腐殖化指数(HIX)更接近于壤中流;流域水体解析出DOM含有3种类腐殖酸类物质和一种类色氨酸类物质;结合稳定同位素混合(SIAR)模型,李家河水库水体污染物来源以土壤、肥料及凋落物为主,其对DOM及硝酸盐主要贡献率分别达到68%左右和77%左右.该研究对未来开展精准治污等水环境保护措施提供了参考依据.

Abstract

As an important water supply source,reservoirs are faced with water quality problems such as eutrophica-tion and oxygen-consuming organic matter pollution.In view of the pollutants source analyzing of reservoir water is a fundamental basis for precise pollution control and scientific management,the study was conducted using meth-ods of hydro-chemical composition analysis,three-dimensional fluorescence spectrum combined with parallel factor analysis and nitrogen and oxygen stable isotopes combined with Bayesian model,alongside with the Bayesian model to trace DOM(dissolved organic matter)and nitrate.The result showed that fluorescence index FI of water bodies in Lijiahe Reservoir in dry season was higher than in wet season,and the index HIX of DOM in the upstream streams of the reservoir was close to that of sub-surface flow during dry season;it was identified that DOM contained three kinds of humic acid substances and one kind of tryptophan substances in the Reservoir;and according to SIAR mod-elling result,it was showed that soil,fertilizer and litters were the main sources of water pollutants into the Reservoir,and their main contribution rates to DOM and nitrate reached about 68%and 77%,respectively.It is hoped that this study could provide a reference for water environmental protection with precise pollution control measures in the years to come.

关键词

污染物溯源/溶解性有机物/硝酸盐/SIAR模型/李家河水库

Key words

pollutant traceability/dissolved organic matter/nitrate/SIAR model/Lijiahe Reservoir

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出版年

2024
环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
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