环境科学与技术2024,Vol.47Issue(11) :178-184.DOI:10.19672/j.cnki.1003-6504.1224.24.338

响应曲面法优化酸热联合预处理改善污泥脱水性能的研究

Optimization of Acid-heat Combined Pre treatment to Improve Sludge De-watering Performance Using Response Surface Methodology

于晓艳 李玉玉 苏赛赛 杜苏萌
环境科学与技术2024,Vol.47Issue(11) :178-184.DOI:10.19672/j.cnki.1003-6504.1224.24.338

响应曲面法优化酸热联合预处理改善污泥脱水性能的研究

Optimization of Acid-heat Combined Pre treatment to Improve Sludge De-watering Performance Using Response Surface Methodology

于晓艳 1李玉玉 2苏赛赛 1杜苏萌1
扫码查看

作者信息

  • 1. 太原工业学院环境与安全工程系,山西 太原 030008
  • 2. 山西大学环境与资源学院,山西 太原 030031
  • 折叠

摘要

该研究通过酸热联合预处理的方式破解污泥絮体结构以改善污泥的脱水性能,同时基于Box-Behnken响应曲面法对污泥脱水模型进行预测并进行参数优化.结果表明,酸热联合预处理可极大地改善污泥的脱水能力,且当pH为1.0、59.2 ℃加热34.1 min时,污泥的脱水能力最佳,此时泥饼脱水后的含水率为59.0%,污泥比阻SRF为7.48×1012m/kg.酸热联合预处理改善污泥的脱水性能,主要通过大量紧密型胞外聚合物(TB-EPS)转化为溶解型胞外聚合物(S-EPS)和松散型胞外聚合物(LB-EPS)以改变污泥表面的电荷,且TB-EPS蛋白质减少的量近似等于S-EPS和LB-EPS蛋白质增量之和.同时酸热联合作用下污泥颗粒粒径明显增大,而污泥游离氨基酸的种类和浓度对其脱水性能的影响较小.

Abstract

Acid-heat pretreatment was used to improve the sludge dewatering performance by breaking the structure of sludge flocs,and a mathematical model simulated about sludge de-watering capability was obtained,besides the relevant factors were optimized based on the Box-Behnken response surface method.The results showed that acid-heat combined pretreatment could greatly improve the sludge dewatering performance,and it was optimized in the case of a pH of 1.0 and temperature of 59.2℃ for 34.1 min,the water content of sludge cake reached as low as 59.0%and SRF was 7.48×1012 m/kg.In terms of mechanism,the acid-heat combined pretreatment improved the de-watering performance of sludge mainly through the conversion of a large amount of tightly bound extracellular polymetric substances(TB-EPS)to soluble extracellular polymetric substances(S-EPS)and loosely bound extracellular polymetric substances(LB-EPS)to change the surface charge of sludge,reducing the amount of protein in TB-EPS,approximately equal to the increasing amount of protein in both S-EPS and LB-EPS.And particle size of sludge greatly enlarged under acid-heat combined pretreatment,but the type and concentra-tion of free amino acids in sludge had relatively lesser impact on its dewatering performance.

关键词

污泥脱水/表面电荷/酸热耦合/响应曲面法/氨基酸

Key words

sludge de-watering/surface charge/acid-heat coupled/response surface method/amino acid

引用本文复制引用

出版年

2024
环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
段落导航相关论文