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基于蒙特卡洛模拟的甘曲湿地重金属风险评价

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甘曲湿地是拉萨河流域代表性的河谷湿地,为了解该湿地重金属分布特征和环境风险,作者共采集22个沉积物样品,对8种重金属(Cd、Hg、As、Pb、Cr、Cu、Ni和Zn)含量进行分析,采用地累积指数、Hakanson潜在生态风险指数法进行风险评价,并与蒙特卡洛模拟(Monte-Carlo)相耦合对研究区生态风险进行定量评估,进一步利用绝对主成分得分-多元线性回归模型(APCS-MLR)对重金属来源进行解析.结果表明:湿地沉积物中Cd、Hg、As、Pb、Cr、Cu、Ni和Zn元素含量分别为0.15、0.04、15.05、33.49、47.36、22.00、19.18和76.41mg/kg,其中As、Ni和Cr元素含量低于西藏背景值,而Cd、Hg、Pb、Cu和Zn元素分别是背景值的1.88、1.54、1.16、1.00、1.04倍;地累积指数显示,Cd(0.54)为轻度污染,其他元素均为无污染;综合生态风险指数为141.74,研究区整体为低生态危害,但潜在生态危害指数结果显示,Cd和Hg分别存在78.49%、67.64%的概率为中等生态危害,是引起生态风险的主要因子.APCS-MLR模型源解析可知,自然源对Cu、Cr、Ni、Zn和Pb的贡献率分别为86.09%、97.08%、86.36%、74.97%、75.42%,农业源对Cd、As和Hg的贡献率分别为72.07%、67.30%和50.34%,同时Hg还受到49.66%自然源贡献,表明Hg元素受到2个来源的共同影响.
Risk Assessment of Heavy Metals in Ganqu Wetland Based on Monte-Carlo Simulation
Ganqu Wetland is a representative valley wetland in the Lhasa River Basin.In order to understand the distribution characteristics and environmental risks of heavy metals in the wetland,a total of 22 sediment samples were collected.The contents of eight heavy metals(Cd,Hg,As,Pb,Cr,Cu,Ni and Zn)were analyzed.The geo-accumulation index and Hakan-son potential ecological risk index were used for risk assessment,and the ecological risk in the study area was quantitative-ly assessed by coupling with Monte-Carlo simulation.Absolute principal component score-multiple linear regression model(APCS-MLR)was further used to analyze the sources of heavy metals.The results showed that the contents of Cd,Hg,As,Pb,Cr,Cu,Ni and Zn in wetland sediments were 0.15,0.04,15.05,33.49,47.36,22.00,19.18 and 76.41 mg/kg,respec-tively.The contents of As,Ni and Cr were lower than the background values of Tibet,while the contents of Cd,Hg,Pb,Cu and Zn were 1.88,1.54,1.16,1.00 and 1.04 times of the background values,respectively.The geo-accumulation index showed that except for Cd(0.54),other elements were non-polluting.The comprehensive ecological risk index(RI)was 141.74,and the overall ecological risk in the study area was low.However,the results of the potential ecological risk index showed that Cd and Hg had a probability of 78.49%and 67.64%,respectively,which were medium ecological hazards and were the main factors causing ecological risks.The source apportionment of APCS-MLR model showed that the contribution rates of natural sources to Cu,Cr,Ni,Zn and Pb were 86.09%,97.08%,86.36%,74.97%and 75.42%,respectively.The contri-bution rates of agricultural sources to Cd,As and Hg were 72.07%,67.30%and 50.34%,respectively.At the same time,Hg was also contributed by 49.66%of natural sources,indicating that Hg was affected by both sources.

Ganqu Wetlandsedimentsheavy metalsMonte-Carlorisk assessmentAPCS-MLR

李伟、杨博、熊健、周海洋、唐宏材、孙晶、吕学斌

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西藏大学生态环境学院,西藏 拉萨 850000

天津大学环境科学与工程学院,天津 300350

甘曲湿地 沉积物 重金属 Monte-Carlo 风险评价 APCS-MLR

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(11)