首页|生物炭负载硫化纳米零价铁在环境修复中的应用研究进展

生物炭负载硫化纳米零价铁在环境修复中的应用研究进展

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纳米零价铁颗粒(nZVI)被认为是一种修复污染土壤和水环境的优良材料,可应用于多种污染物的原位修复。然而,nZVI颗粒易团聚和易氧化的缺点,明显降低了其对污染物的修复性能。生物炭因具有较高的比表面积、稳定的多孔结构和较多的表面活性位点,成为分散nZVI的有效载体。另外,硫化修饰的方式可以有效缓解nZVI颗粒团聚和抑制nZVI颗粒的氧化。因此,生物炭负载硫化纳米零价铁复合材料(S-nZVI@BC)可以有效提高nZVI颗粒的分散性和稳定性,缓解nZVI的表面氧化,同时提高nZVI的电子传导率,控制nZVI的腐蚀速率,从而提高对污染物的去除率,使nZVI具有更强的反应活性和目标污染物选择性。该文详细总结了 S-nZVI@BC的制备方法及其表征技术,介绍了 S-nZVI@BC修复重金属和有机污染物的最新进展,讨论了环境因素对其修复性能的影响,探究其去除污染物的机制并提出改进其性能的建议,可为S-nZVI@BC在环境修复中的应用提供理论指导。
Research Progress in Application of Biochar-supported Sulfidized Nanoscale Iron Composites to Environmental Remediation
Nanoscale zero valent iron(nZVI),regarded as an excellent material for remediation of contaminated soil and water bodies,can be used for the in-situ remediation of various pollutants;however,the drawbacks of easy aggregation and oxidation of nZVI considerably reduce its remediation performance.Biochar,having a high specific surface area,stable porous structure,and numerous surface active sites,is an effective carrier for dispersing nZVI particles;besides,sulfuration modifica-tion can effectively alleviate the agglomeration of nZVI particles and inhibit the oxidation of nZVI particles.Therefore,biochar-supported sulfurized nano-zero valent iron(S-nZVI@BC)composite is able to effectively improve the dispersion and stability of nZVI particles,and characterized with alleviating surface oxidation of nZVI,improving the electronic conduc-tivity of nZVI,and controlling the corrosion rate of nZVI,which can improve pollutants removal rate and enable nZVI to be stronger in terms of reactivity and target pollutant selectivity.This paper is dedicated to summarize in detail the preparation method and characterization technology of S-nZVI@BC),introducing the latest progress in the removal of heavy metals and organic pollutants by S-nZVI@BC.In addition,the influence of environmental factors on their remediation performance is discussed,the remediation mechanism of S-nZVI@BC for pollutant is explored;in the end,suggestions for improving remediation performance of S-nZVI@BC are proposed,which is aimed to offer theoretical guidance for the application of S-nZVI@BC in environmental remediation.

S-nZVIbiocharremediation performanceremoval mechanismapplication prospect

张依诺、杨君豪、孙漱玉、倪雅群、孔强、张焕新、刘继伟

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山东师范大学地理与环境学院,山东 济南 250000

山东师范大学东营研究院,山东 东营 257000

硫化纳米零价铁 生物炭 修复性能 去除机制 应用前景

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(12)