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GPMAS测定土壤中亚硝酸盐氮的干扰探讨

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文章探讨了气相分子吸收光谱法测定土壤中亚硝酸盐氮时,硫化物、甲醛、VOCs、乙草胺、丙烯酰胺、尿素等土壤中存在的物质对分析可能产生的干扰及干扰去除方法。实验结果表明,硫化物、VOCs对亚硝酸盐氮的测定结果产生正干扰。土壤提取液中加入乙酸锌+乙酸钠混合溶液并将溶液调为弱碱性(pH 10~11),可消除硫化物干扰;土壤提取液加热煮沸3~5 min,可消除VOCs的干扰。甲醛、乙草胺、丙烯酰胺、尿素基本无干扰。
Discussion on Interference of Soil Nitrite Nitrogen Determination by GPMAS
The paper discussed the possible interference and removal methods of sulfide,formaldehyde,VOCs,acetochlor,acrylamide,urea and other substances in the determination of nitrite nitrogen in soil using gas phase molecular absorption spectroscopy.The experimental results show that sulfide and VOCs have a positive interference on the determination of nitrite nitrogen.When a mixed solution of zinc acetate and sodium acetate is added to the soil extraction solution and the solution is ad-justed to weak alkalinity(pH 10~11),sulfide interference can be eliminated.Heating and boiling the soil extract for 3~5 min-utes can eliminate the interference of VOCs.Formaldehyde,acetochlor,acrylamide,and urea have basically no interference.

gas phase molecular absorption spectroscopysoilnitrogeninterferenceelimination

杨登、陈英、贺小敏、王卉、廖华英

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湖北省生态环境厅恩施州生态环境监测中心,湖北 恩施 445000

湖北省生态环境监测中心站,湖北 武汉 430071

恩施市环境监测站,湖北 恩施 445000

气相分子吸收光谱法 土壤 亚硝酸盐氮 干扰 消除

湖北省地方标准制修订项目

T-Z-06-2021276

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(z1)