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高镍玄武岩地质背景区土壤镍安全阈值的研究

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玄武岩是高镍地质体,现行的农用地土壤环境质量标准并不完全适用于这些高地质背景地区土地评价。该研究以浙江新昌玄武岩台地为研究区,在对区域主要作物(茶叶)进行健康风险评估的基础上,结合种子发芽和藻类镍毒性实验,探究制定高镍地质背景地区土壤镍的安全阈值。结果表明,基于现行国家标准评价的土壤分级结果与作物健康风险评价结果存在显著不一致。培养实验表明,水中活性Ni达到0。74mg/L时,显现生物毒性。根据含水量和水溶性Ni与活性Ni的比例,测算得出玄武岩台地土壤有效Ni的安全阈值为1。73mg/kg,总Ni的安全阈值为100。46mg/kg。基于我们推荐的Ni安全阈值对本区土壤进行了重新评价,结果与实际情况较为吻合。
Study on the Safety Threshold of Soil Nickel in High Nickel Basalt Geological Background
Basalt is a high nickel geological body.The existing soil environmental quality standards for agricultural land are not fully applicable to land evaluation in these areas with high geological background.Based on the health risk assessment of the main crops(tea)in Xinchang basalt platform,Zhejiang Province,and combined with seed germination and nickel toxicity experiments of algae,this study explored and established the safety threshold of soil nickel in the area with high nickel geolog-ical background.The results showed that the soil classification results based on the current national standards were significant-ly inconsistent with the crop health risk assessment results.The culture experiment showed that biotoxicity appeared when Ni in water reached 0.74 mg/L.Based on the soil water content and the ratio of water-soluble Ni to active Ni,the safety threshold of available Ni and total Ni on basalt platform were estimated to be 1.73 mg/kg and 100.46 mg/kg respectively.The soil in this area was reevaluated based on the recommended Ni safety threshold,and the results are in good agreement with the actual situation.

nickelbasalt platformtoxicityeffective Nitotal Nisafety threshold

陈飞洋、刘煜、黄永亮、周思儒、柴梦婷、向武

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中国地质大学武汉地球科学学院,湖北 武汉 430000

浙江有色地勘集团有限公司,浙江 绍兴 312000

玄武岩台地 毒性 有效Ni 全Ni 安全阈值

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(z1)