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铬盐厂重金属生物可给性及健康风险研究

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文章以某铬盐厂污染土壤中的铬(Cr)、镍(Ni)、铜(Cu)、铅(Pb)为目标物,采用德国标准研究院体外法(DIN-19738),研究了不同进食状况对重金属生物可给性的影响;基于生物可给性,计算了经口摄入途径下场地超标污染物Cr的暴露量及人体健康风险。研究结果表明:场地土壤中检出的4种重金属只有Cr超标,浓度范围在9。06×103~8。07×104 mg/kg之间;Pb、Ni和Cr肠相中生物可给性低于胃相,而Cu肠相中生物可给性高于胃相;Cr和Ni在禁食下的生物可给性高于进食条件下的生物可给性,Pb和Cu则正好相反;基于生物可给性计算土壤中Cr暴露量和人体健康风险均有不同程度的降低。
Bioaccessibility and Health Risk of Heavy Metals in a Chromium Salt Plant
Taking chromium(Cr),nickel(Ni),copper(Cu),and lead(Pb)in the contaminated soil of a chrome salt factory as the target,the deutsches institut für normung(DIN-19738),the effects of different feeding conditions on the bioavailability of heavy metals were studied.Based on the bioavailability of Cr,human health risks under the oral intake exposure pathway were calculated.The results showed that only Cr was detected in the soil of the site,and the concentration ranged from 9.06×103 to 8.07×104 mg/kg;the bioavailability in the enteric phase was lower than that in the gastric phase for Pb,Ni and Cr,and higher than that in the gastric phase for Cu;the bioavailability in fasting was higher than that in feeding for Cr and Ni,and vice versa for Pb and Cu;and the bioavailability based on the bioavailability of Cr was higher than that of Cr and Ni in fasting,and vice versa for Cu.The opposite was true for Pb and Cu;Cr exposures and human health risks in soil based on bioavailability were reduced to varying degrees.

heavy metalbioaccessibilityDIN in vitro method

郭晓欣、张超艳、熊杰、范婧婧、周友亚

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生态环境部土壤与农业农村生态环境监管技术中心,北京 100012

河北师范大学化学与材料科学学院,河北 石家庄 050024

重金属 生物可给性 DIN体外法

国家自然科学基金项目国家重点研发计划(土壤专项)项目

419773772018YFC1803001

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(z1)