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某肥料厂地块土壤重金属污染分布及风险研究

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为揭示肥料生产场地土壤重金属污染状况及分布特征,该研究以湖北某肥料厂遗留地块为对象,对23个点位共计80份土壤样品进行检测分析。结果表明:该地块能检出As、Cd、Cu、Pb、Hg、Ni及Cr6+等7种重金属,其中As浓度区间为18。9~176 mg/kg,超过《土壤环境质量建设用地土壤污染风险管控标准(试行)》(GB 36600-2018)标准中第二类用地筛选值的样品率达56。25%;受检土壤样品中As的最大单因子污染指数、地质累积指数和潜在生态危害指数分别为2。93、3。14和132。33,被归类为中度污染、偏重度污染和较强生态风险;典型点位As垂直污染深度超过5。4 m,这与地块表层素填土不利于As的截留,使其以溶解态的形式随雨水径流向深层迁移有关;对地块土壤进行人体健康风险评估,得到As的总致癌风险为1。2E-04,非致癌风险危害商为2。10,远超过人体可接受水平,建议使用水泥窑协同处置技术进行治理修复。
Study on the Distribution Characteristics and Health Risks of Heavy Metal Pollution in the Soil of a Fertilizer Factory Legacy Site
To reveal the status and distribution characteristics of heavy metal pollution in the soil of fertilizer production sites,this study focused on the legacy site of a fertilizer factory in Hubei,and detected and analyzed a total of 80 soil samples from 23 locations.The results show that 7 heavy metals could be detected on the site,including As,Cd,Cu,Pb,Hg,Ni,and Cr6+.The concentration range of As was between 18.9~176 mg/kg,which exceeded the second type of land screening value of the Soil Environmental Quality:Risk Control Standard for Soil Contamination of Development Land(GB 36600-2018),with a sample rate of 56.25%.The maximum single factor pollution index,geo-accumulation index,and potential ecological risk index of As among the tested soil samples were 2.93,3.14,and 132.33,respectively,which were classified as moderate pollu-tion,near-heavy pollution,and near-strong ecological risk,respectively.The vertical As pollution depth of typical sites exceeded 5.4 m,which was related to the reason that the surface plain fill of the site was not conducive to the interception of As,causing it to migrate in a dissolved state with the rainwater runoff towards the deep layer.A human health risk assessment was conducted on the soil of the site,and it was found that the total carcinogenic risk of As was 1.2E-04,and the non-carcino-genic risk hazard quotient was 2.10,which far exceeded the acceptable levels for human health.The cement kiln collaborative disposal technology was recommended to use for this site remediation.

fertilizer plantlegacy sitesoil pollutionheavy metalshuman health risk

许浩瀚、蔡忠丽、丁佳雨、李虹呈、屈弋雯、余晶晶

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湖北省生态环境科学砑究院(省生态环境工程评估中心),湖北 武汉 430072

江汉大学环境与健康学院,湖北 武汉 430056

武汉市黄陂区农业检验检测所,湖北 武汉 430030

肥料厂 遗留地块 土壤污染 重金属 人体健康风险

2024

环境科学与技术
湖北省环境科学研究院

环境科学与技术

CSTPCD北大核心
影响因子:0.943
ISSN:1003-6504
年,卷(期):2024.47(z1)