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典型钢铁冶炼场地重金属污染空间分布特征及风险评价

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以上海某关停钢铁冶炼厂为研究对象,结合专业判断布点法与系统布点法布设83个土壤点位,采集表、中、深层共249个土壤样品,分析As、Pb、Cd、Ni、Hg、Cu这6种重金属的分布特征、污染状况、潜在生态风险及健康风险.结果表明,As、Pb出现部分样品超标,Cd、Pb为强变异,其他重金属变异程度中等;重金属平均含量在垂向上呈现自上而下逐渐降低的趋势,且最高值均分布在表层,累积区域主要为扒渣厂房、钢渣处理区和废钢配料间;地累积指数评价结果显示,Cd和Pb的污染相对较为严重,重污染及以上的样品比例分别为8.43%、3.61%.潜在生态风险评价结果显示,场地整体的生态风险较高,Cd为主要贡献因子,较强风险及以上的样品占比高达51.81%;人体健康风险评价结果显示,Pb、As和Cd可能对人体产生一定的健康风险,因此有必要开展土壤的风险管控或修复以保证场地的再开发利用.
Spatial distribution characteristics and risk assessment of heavy metal pollution in a typical steel smelting site
A shutdown steel smelter in Shanghai was took as the research object,and 249 soil samples in the surface,middle and deep layers were collected from 83 sampling points to analyze the distribution characteristics,pollution status,potential ecological risk and health risk of six heavy metals(As,Pb,Cd,Ni,Hg and Cu).The sampling points were chosen by professional and systematic layout methods.The results showed that the concentrations of As and Pb in some samples exceeded the standard;Cd and Pb showed strong variation,and the variation of other metals was moderate.The average concentrations of heavy metals showed a trend of gradual decrease from top to bottom in vertical distribution,and the highest concentrations were all distributed in the surface soil.Heavy metals were mainly enriched in the slag removal room,steel slag treatment area and scrap steel batching room.The evaluation results of the ground accumulation index showed that some samples of Cd and Pb were extremely severely polluted,the proportion of samples with severe pollution or above was 8.43%and 3.61%,respectively.The evaluation of potential ecological risk showed that the overall ecological risk of the site was high,with Cd as the main contributing factor and 51.81%of the samples with relative high risk or above.Health risk assessment showed that Pb,As and Cd might pose health risk to human,thus it was necessary to carry out soil management or remediation to ensure the redevelopment and utilization of the site.

steel smelting siteheavy metal pollutionspatial distributionecological riskhealth risk assessment

黄波涛、钱诗颖、叶文娟

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上海市环境科学研究院,上海 200233

钢铁冶炼场地 重金属污染 空间分布 生态风险 健康风险评价

上海市环境科学研究院创新基金

CX2021180327

2024

环境污染与防治
浙江省环境保护科学设计研究院

环境污染与防治

CSTPCD北大核心
影响因子:0.79
ISSN:1001-3865
年,卷(期):2024.46(1)
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