首页|低SO2氧化率钒钛基选择性催化还原脱硝催化剂研究进展

低SO2氧化率钒钛基选择性催化还原脱硝催化剂研究进展

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选择性催化还原(SCR)脱硝技术是目前烟气氮氧化物控制最主流的技术.商用SCR催化剂主要由V2O5-WO3(MoO3)/TiO2组成,其中V2O5不仅对烟气中的氮氧化物有催化还原作用,同时也能促进SO2的氧化,导致硫酸铵盐的生成,进而造成催化剂孔道堵塞,活性位点减少,使催化剂活性降低,脱硝效率下降.基于此,主要探讨了钒钛基SCR催化剂对SO2的氧化机理及其研究进展,总结了国内外降低钒钛基SCR催化剂SO2氧化率的一些主要措施,并对此进行了分析和讨论.
Research progress of vanadium titanium based selective catalytic reduction denitration catalyst with low SO2 oxidation rate
Selective catalytic reduction(SCR)denitration technology is currently the most mainstream technology for controlling nitrogen oxides in flue gas.Commercial SCR catalyst is mainly composed of V2 O5-WO3(MoO3)/TiO2.V2O5 not only has catalytic reduction effect on nitrogen oxides in flue gas,but also can promote the oxidation of SO2,resulting in the formation of ammonium sulfate,which leads to the blockage of catalyst channels,the reduction of active site,the reduction of catalyst activity and the reduction of denitrification efficiency.This article mainly explored the oxidation mechanism and research progress of SO2 in vanadium titanium based SCR catalysts,summarized some main measures to reduce the SO2 oxidation rate of vanadium titanium based SCR catalysts at home and abroad,and analyzed and discussed this issue.

selective catalytic reductiondenitrificationvanadium based catalystSO2 oxidation rate

陈校艺、赵博、李浙飞、柯权力、周瑛、卢晗锋

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浙江工业大学环境学院,环境生态与工程研究所,浙江 杭州 310014

浙江德创环保科技股份有限公司,浙江 绍兴 312000

浙江工业大学化学工程学院,催化反应工程研究所,浙江 杭州 310014

选择性催化还原 脱硝 钒基催化剂SO2氧化率

绍兴市产业关键技术攻关计划浙江省自然科学基金浙江省自然科学基金

2022B41007LZ21E080001LGF20E080018

2024

环境污染与防治
浙江省环境保护科学设计研究院

环境污染与防治

CSTPCD北大核心
影响因子:0.79
ISSN:1001-3865
年,卷(期):2024.46(1)
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