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不同理化性质的土壤对地下水中柴油的吸附行为研究

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采用静态吸附实验研究不同理化性质的土壤对溶液中柴油的吸附行为。结果表明:不同理化性质的土壤对柴油的吸附均可以在24 h内达到平衡,准二级动力学模型(R2为0。92~1。00)能更好地描述土壤对柴油的吸附动力学数据,吸附过程以化学吸附为主,液膜扩散和颗粒内扩散共同影响吸附反应的控速步骤。吸附等温线符合Langmuir模型,表明柴油在土壤中的吸附为单分子层吸附,近似于不可逆型吸附。被石油污染的场地土对水体中柴油的吸附量小于未被污染的林地土,土壤对液相中柴油的吸附量与有机质含量呈正相关,并随着土壤粒径和pH的减小而逐渐增大。
Study on the adsorption behavior of diesel oil in groundwater by soils with different physicochemical properties
The static adsorption experiment was conducted to study the adsorption behavior of diesel oil in water by soil with different physicochemical properties.The results showed that the adsorption kinetics of diesel oil on soils with different physical and chemical properties could reach equilibrium within 24 h.The quasi-second-order kinetic model(R2was 0.92-1.00)could better describe the adsorption kinetics of diesel oil on soils.The adsorption process was dominated by chemical adsorption.The adsorption isotherm was consistent with the Langmuir isotherm adsorption model,indicating that the adsorption of diesel oil on soil was monolayer adsorption,which was similar to irreversible adsorption.The amount of diesel oil adsorbed by oil polluted soil was less than that by unpolluted forest soil.The amount of diesel oil adsorbed by soil in water was positively correlated with the content of organic matter,and gradually increased with the decrease of soil particle size and pH.

diesel oiladsorption kineticsadsorption isotherminfluencing factor

张天琦、黄岁樑、李玲、郭智、李高成

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环境污染过程与基准教育部重点实验室,天津市城市生态环境修复与污染防治重点实验室,南开大学环境科学与工程学院,天津 300071

柴油 吸附动力学 吸附等温线 影响因素

国家重点研发计划项目

2020YFC1808804

2024

环境污染与防治
浙江省环境保护科学设计研究院

环境污染与防治

CSTPCD北大核心
影响因子:0.79
ISSN:1001-3865
年,卷(期):2024.46(4)
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