首页|气象要素与前体物排放对中国区域性臭氧污染的影响

气象要素与前体物排放对中国区域性臭氧污染的影响

扫码查看
2022年9月,中国出现了多次区域性臭氧污染过程,污染较重的区域主要集中于华南与华北.全国339个城市中,共出现了 1 844天次的臭氧超标情况,其中重度污染3天次(均出现在珠三角)、中度污染123天次、轻度污染1 718天次.中国华北与华南等地长期处于台风外围下沉气流影响区,容易出现持续干燥少雨、风速偏低、气温持续偏高的气象特征,有利于臭氧的生成与积累,是造成该时期臭氧污染过程持续时间长、影响范围广、污染程度重的重要原因.臭氧超标天数较多的城市一般具有较高的NO2浓度与挥发性有机化合物臭氧生成潜势(OFP),其中NO2一般在30 μg/m3左右、OFP一般超过100 μg/m3,通过相关性分析与多元线性回归方法,得出区域性臭氧污染受NO2影响更显著的结论.可见,当前中国华南与华北等地臭氧前体物排放量仍较大,在不利气象条件下,臭氧前体物累积加剧了臭氧污染.
Impacts of meteorological conditions and precursor emissions on regional ozone pollution in China
In September 2022,China experienced multiple regional ozone pollution processes,and the heavily polluted areas were mainly concentrated in South and North China.Out of 339 cities across the country,a total of 1 844 days/times of ozone exceeding standards occurred,including 3 days/times of severe pollution(all in the Pearl River Delta),123 days/times of moderate pollution,and 1 718 days/times of mild pollution.The downdraft outside the typhoon in September 2022 affected both North and South China for an extended period of time.This downdraft was prone to meteorological conditions that were extremely favorable for the generation and accumulation of ozone,including continuous dryness with little rain,low wind speed and persistently high temperature.It was a significant factor in the ozone pollution process,leading to extended duration,broad impact range,and high pollution level.Cities with a higher number of days experiencing excessive ozone often had higher levels of NO2 and VOCs ozone formation potential(OFP),with OFP of more than 100 μg/m3 and NO2 of roughly 30 μg/m3.Correlation analysis and multiple linear regression results indicated that NO2 emissions were mostly responsible for the regional ozone pollution.These indicated that ozone precursor emissions were still occurring at high levels in North and South China,and that ozone pollution was made worse by the buildup of ozone precursors during unfavorable weather.

Chinaozonepollution processcauses

赵熠琳、李子、沈劲、王威、朱媛媛、丁俊男、高愈霄

展开 >

中国环境监测总站,北京 100029

生态环境部南京环境学科研究所,江苏 南京 210042

广东省生态环境监测中心,国家环境保护区域空气质量监测重点实验室,广东省环境保护大气二次污染研究重点实验室,广东 广州 510308

中国 臭氧 污染过程 成因

国家重点研发计划项目

2017YFC0212705

2024

环境污染与防治
浙江省环境保护科学设计研究院

环境污染与防治

CSTPCD北大核心
影响因子:0.79
ISSN:1001-3865
年,卷(期):2024.46(6)
  • 2