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改性多壁碳纳米管对水中Cd~(2+)的去除

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为了增加多壁碳纳米管(multiwall carbon nanotubers,MWNTs)对水中Cd2+的吸附量,使用混酸对多壁碳纳米管进行氧化处理,采用红外光谱进行结果表征,并探讨了吸附时间、pH值和MWNTs的使用量、Cd2+的浓度及干扰离子对镉离子吸附的影响。结果表明,吸附时间为1.5 h、pH为5.3、吸附效果最佳,随MWNTs量的增加Cd2+去除量增加,共存的阳离子会降低对Cd2+的吸附效果,对Cd2+的吸附符合Longmuir吸附定律。研究同时表明,pH小于2时Cd2+能容易从碳纳米管上解吸。初步探讨了Cd2+吸附机制。
Removal of Cd~(2+) from water by modified multiwall carbon nanotubers
In order to increase the adsorption amount of Cd2+ in water,the multiwall carbon nanotubers were treated by mixed acid,and the result was characterized by IR.The treated MWNTs were used to adsorb the Cd2+ in simulating water.The effect of adsorption time,pH,the amount of MWNTs,the concentration of Cd2+ and interfering ion on the adsorption of Cd2+ were discussed.The results indicated that optimal conditions of Cd2+ adsorption on treated MWNTs were time of 1.5 h and pH of 5.3.The amount of Cd2+ adsorption increased with increase of the amount of MWNTs,and effect of adsorption was depressed by existence of cation,the adsorption data fit the langmiur model and its linearized form well.Results of a desorption study showed that Cd2+ adsorbed onto MWCNTs could be easily desorbed at pH 2.The mechanism of Cd2+ adsorption was also discussed.

muiltiwall carbon nanotubersadsorptiondesorptionCd2+ ionswater treatment

杨铁金、马伟光、刘亚红、张华、张艳

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齐齐哈尔大学化学与化学工程学院,齐齐哈尔161006

多壁碳纳米管 吸附 解吸 Cd2+ 水处理

2012

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCDCSCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2012.6(5)
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