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热解工艺对污泥制备生物炭物理结构的影响

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热解污泥制备生物炭是一种污泥资源化利用的主要处置方式,不同的反应条件对制得生物炭的品质存在显著的差异.以乙酸钾为添加剂,对城市脱水污泥(含水率80%)进行低温热解制备生物炭,考察了乙酸钾添加量、热解温度、热解停留时间及升温速率对生物炭性质的影响.通过N2吸附脱附、SEM、FT-IR等手段对原料污泥及生物炭进行了表征,实验结果表明,乙酸钾具有一定的扩孔作用,生物炭表面粗糙度明显增加,比表面积增大,吸附性能显著提高.当乙酸钾添加量4%,热解温度350℃,热解停留时间120 min,升温速率3℃·min-时生物炭的亚甲基蓝吸附量和比表面积分别为90.45 mg·g-1、31.402 m2· g-1.
Effect of pyrolysis process on physical structure of biochar
Converting sewage sludge to biochar is one of the main ways to achieve sludge recycling.However,significant differences in the properties of biochar were observed due to different pyrolysis conditions.In this work,the preparation of biochar was investigated using low temperature pyrolysis of municipal sludge (moisture content 80%) with potassium acetate as an active agent.The aim of this study was to systematically investigate the effect of pyrolysis conditions,such as potassium acetate dosage,temperature,hold time,and heating rate of the sludge biochar.Because the addition of potassium acetate increased the activation ability of the sludge,the surface roughness and BET area of the biochar were increased.The results show that the most feasible conditions under which to produce adsorbents is the concentration of the potassium acetate dosage 4%,reaction temperature 350 ℃,reaction time 120 min,and heating rate of 3 ℃ · min-1 Under these conditions,the methylene blue adsorption number and BET area were 90.45 mg · g-1 and 31.402 m2 · g-1.

low-temperature pyrolysissludgebiochar

王格格、李刚、陆江银、王建俊

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新疆大学化学化工学院石油与天然气精细化工教育部重点实验室,乌鲁木齐830046

新疆乌鲁木齐昆仑环保集团有限公司,乌鲁木齐830021

低温热解 污泥 生物炭

新疆维吾尔自治区乌鲁木齐市科技计划项目

Y131330011

2016

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCDCSCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2016.10(12)
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