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木质素磺酸盐型煤的制备及其性能

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型煤是洁净煤技术的一个重要组成部分,其中廉价、低灰分型煤粘结剂是型煤生产的关键技术.以造纸工业产生的固体废弃物木质素磺酸盐为原料,通过化学方法处理制备粘合剂并应用于型煤的压制,探索木质素磺酸盐资源化利用新途径.对木质素磺酸盐的形貌和元素组成进行了分析,优化了粘合剂原料的比例,考察了胶煤比、高径比、压制压力和压制时间对型煤的影响规律,最后对型煤的抗磨、抗淋和抗浸泡及燃烧性能进行了评价.结果表明:原料木质素磺酸盐为粒状团聚态,通过碱作用制备粘合剂时m(水)∶m(木质素磺酸盐)∶m(NaOH)适宜质量比为39∶ 10∶1;型煤适宜工艺参数为胶煤质量比为9∶50、型煤高径比保持1∶1、压制压力20 MPa和压制时间10 min,此时型煤落下强度可达95%以上,同时其抗磨强度可达90%.从灰分形态及CO2排放证实型煤燃烧转化效率明显提高,且烟气中NOx和CO污染物排放浓度明显降低,达到了节能环保的目的.
Preparation and performance of briquette from lignosulfonate
Briquettes are an important component of clean coal technology.Cheap,low ash coal adhesive is the key technology of briquette production.An adhesive was prepared using lignosulfonate,which is produced as a raw material in the papermaking industries,and was applied to coal briquetting.This new method of recycling lignosulfonate is of great significance.The morphology and elemental composition of lignosulfonate was characterized by a scanning electron microscope and element analysis.The technological parameters for coal briquetting were optimized.Tests for measuring abrasion,drench,and soak resistances,and combustion performance of the briquette were performed.Results indicate that lignosulfonate exists in a granular aggregate state,and the optimum mass ratio for lignosulfonate adhesives of water:lignosulfonate:NaOH is 39∶10∶1.For coal briquetting,the adhesive-coal ratio is 9 ∶ 50 and the ratio of height-to-diameter for a briquette is 1 ∶ 1.Under 20 MPa for 10 minutes,shatter strength of the briquette was over 95% and abrasion resistance was above 90%.Ash patterns and CO2 emissions prove that the combustion efficiency of the briquette was significantly improved.Moreover,the emission concentrations of NOx and CO were significantly reduced,which is beneficial to energy saving and environmental protection.

lignosulfonateadhesivebriquetteconversion efficiency

陈彦广、王琦旗、韩洪晶、张懿达、宋华、王海英

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东北石油大学化学化工学院,大庆163318

黑龙江省石油与天然气化工重点实验室,大庆163318

木质素磺酸盐 粘合剂 型煤 转化效率

国家自然科学基金资助项目黑龙江省研究生创新项目

51204057YJSCX2015~022NEPU

2017

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCDCSCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2017.11(7)
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