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云南个旧矿区Pb污染稻田土壤钝化修复

Immobilization remeditiaon of Pb-contaminated paddy soils in Gejiu Mining Area, Yunnan

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针对云南个旧矿区铅污染稻田土壤,研究了复合钝化剂S1(纳米活性炭+硅钾钙镁肥)、S2(火山石+钙镁磷肥+有机肥)和叶面硅肥F单一及联合施用共5种不同调控处理(S1、S2、F、S1+F、S2+F)的田间修复效果及对稻米铅累积的影响.结果表明,5种调控措施对水稻均能产生增产效应,其中两种联合处理(S1 +F、S2+F)水稻的增产效果明显优于单一处理(S1、S2、F);经过1个水稻生长周期,5种调控处理土壤pH值较对照均有上升,土壤酸可提取态Pb含量均有降低.与对照相比,S2+F处理水稻增产29.7%,土壤pH上升0.48个单位,土壤酸可提取态Pb降低45.5%,糙米Pb含量降低80.4%、且远低于国家食品卫生标准(GB 2762-2012).采用复合钝化剂S2(火山石+钙镁磷肥)基施与水稻灌浆期和抽穗期分别喷施叶面硅肥F的土壤钝化-农艺联合调控措施能有效阻控个旧矿区污染土壤中Pb的迁移,降低糙米中Pb的含量,提高矿区稻米安全质量,可在Pb污染农田推广应用.
Field experiments were carried out to investigate the effects of composite passivator Sl(activated carbon nanoparticle and silicon-potassium-calcium-magnesium fertilizer), S2 (volcanic rock and calcium-magnesia phosphate fertilizer), and their compound treatments with silicon fertilizer F;on lead (Pb) remediation in paddy soil and Pb accumulation, in the Gejiu mining area of Yunnan Province (PRC).The results showed that application of soil regulator increased the yield of rice, and that soil regulator supplemented with silicon fertilizer treatments appeared more effective than did single treatments for increasing the yield of rice.After a period of rice growth, different treatments increased soil pH values, and reduced the soil acid extractable fraction of Pb.After application of S2 + F, compared with the control group, the rice yield increased by 29.7%, soil pH values increased by 0.48, the soil acid extractable fraction of Pb decreased by 45.5%, and the Pb content of brown rice decreased by 80.4%:A concentration lower than the maximum levels permitted by the Chinese standard for Pb in foods (GB2762-2012).In conclusion, composite passivator S2 combined with silicon fertilizer not only decreased the available Pb in contaminated soil, but also obviously reduced the Pb content in rice, thereby improving the food safety of rice.This compound treatment could provide effective regulation of Pb in the polluted farmland in the Gejiu mining area.

Gejiu mining areacontrol agentsoil remediationleadrice

邓晓霞、黎其万、米艳华、段红平、陈璐、张文波、魏茂琼

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云南省农业科学院质量标准与检测技术研究所,昆明 650221

云南农业大学资源与环境学院,昆明 650223

云南省红河州个旧市大屯镇农业综合服务中心,661077

个旧矿区 调控措施 土壤修复 稻米

农业部公益性行业(农业)专项云南省创新人才培养计划项目云南省创新人才培养计划项目

2013030882014HB0592015HC025

2017

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCDCSCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2017.11(8)
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