首页|PEI-DTC的制备及其对Pb2+、Cu2+、Zn2+的吸附性能

PEI-DTC的制备及其对Pb2+、Cu2+、Zn2+的吸附性能

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以Pb2+吸附量为评价指标获得了 PEI-DTC的最佳制备条件,采用SEM和FT-IR对所制备材料的形貌和结构进行了表征,考察了吸附时间、pH、振荡速度和材料投量对PEI-DTC吸附Pb2+、Cu2+、Zn2+效果的影响,分析了吸附过程中的动力学特征、热力学特征,研究了材料的复用性能.结果表明,采用30%PEI溶液制备PEI-DTC的最佳条件为m(PEI)/m(戊二醛)=2∶1、m(PEI)/m(硼氢化钠)=3∶1、m(PEI)/m(二硫化碳)=3∶1;所制备材料表面呈颗粒状和蜂窝状结构,比表面积较大;PEI-DTC对Pb2+、Cu2+、Zn2+的吸附效果随吸附时间、溶液pH增加呈先快速增加后趋于稳定的变化趋势,Pb2+、Cu2+在100 r·min-1、Zn2+在150 rmin-1时表现出较好的吸附效果,Pb2+在材料投量为0.03 g时即近于完全吸附,而Cu2+、Zn2+在材料投量为0.08 g时仍处于上升趋势;适宜吸附条件下PEI-DTC对Pb2+、Zn2+、Cu2+的去除率分别可达 97.62%、14.79%、78.92%,对应的吸附量分别为 4.005、0.509、4.658 mmol·g-1;PEI-DTC 对 Pb2+、Zn2+、Cu2+的吸附过程符合Langmuir模型和准二级反应动力学模型,吸附为自发的吸热过程;经4次使用,材料对Pb2+的吸附量仍保留81.14%.
Preparation of PEI-DTC and its adsorption performance on Pb2+,Cu,Zn2+
The optimum preparation conditions of PEI-DTC were obtained by taking the adsorption amount of Pb2+as the evaluation index,and the morphology and structure of PEI-DTC were characterized by SEM and FT-IR.The effects of adsorption duration,pH,oscillation speed,and material dosage on the adsorption effect of PEI-DTC to Pb2+,Cu2+,and Zn2+were investigated,and the kinetic,thermodynamic characteristics of the adsorption process,and reuse performance of PEI-DTC were analyzed.The results showed that the optimum preparation conditions of PEI-DTC were m(PEI)/m(glutaraldehyde)=2∶1,m(PEI)/m(NaBH)=3∶1,m(PEI)/m(CS2)=3∶1 when 30%PEI solution was used.The prepared PEI-DTC material had a granular and honeycomb structure with a large specific surface area.The adsorption effect of PEI-DTC on Pb2+,Cu2+,and Zn2+showed a trend of increasing and then stabilizing with the increase of adsorption time and pH,Pb2+,Cu2+showed a better adsorption effect at the oscillations speed of 100 r·min-1,and Zn2+showed a better adsorption effect at the oscillations speed of 150 r·min-1.Pb2+was nearly completely adsorbed at PEI-DTC dosage of 0.03 g,while the removal rates of Cu2+and Zn2+still increased at PEI-DTC dosage of 0.08 g.The removal rates of Pb2+,Zn2+,and Cu2+by PEI-DTC under suitable adsorption conditions were 97.62%,14.79%,and 78.92%,respectively,with the corresponding adsorption amounts of 4.005 mmol·g-1,0.509 mmol·g-1,and 4.658 mmol·g-1,respectively.The adsorption process conformed to Langmuir adsorption isothermal and the quasi-second-order kinetic model.Moreover,Pb2+,Cu2+,and Zn2+adsorption was a spontaneous and endothermic process.The regeneration rate still maintained at 81.14%after four cycles of reuse.

PEI-DTCPb2+Cu2+Zn2+adsorptionreuse performance30%PEI

冯艳平、刘建、李堂姝、兰伟伟

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西南交通大学地球科学与环境工程学院,成都 610031

PEI-DTC Pb2+ Cu2+ Zn2+ 吸附 复用性能 30%PEI

四川省科技计划项目

2021YFG0117

2024

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2024.18(1)
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