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手机用钴酸锂电池循环再生的生命周期评价

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为评估手机用钴酸锂(LCO)电池回收工艺(火法和湿法)和不同分配方法(EoL方法和CFF方法)的环境影响,考虑废电池回收阶段的环境效益,并设定功能单位为钴酸锂电池供电量1 kWh,采用生命周期评价(LCA)方法,对LCO电池开展了从摇篮到坟墓的生命周期评价研究,对EoL和CFF分配方法应用下湿法冶金回收场景的生命周期评价结果进行比较.结果表明,湿法冶金回收工艺的环境效益远大于火法冶金回收工艺,约为火法冶金回收工艺环境效益的2.89倍;对于GWP和FFP以及3种终点法环境损害指标而言,EoL分配的环境效益明显低于CFF分配;主要原因在于EoL分配方法将全部的回收效益计算到首次生命周期之中相比,而CFF分配方法根据市场情况将回收的环境效益在生产可回收材料的生命周期和使用再生材料的生命周期进行合理划分,能够更有效避免环境影响的凭空消失和环境效益的多重计数,影响包括碳排放核算在内的环境影响的科学量化的准确性.同时建议参照欧盟PEF中的锂电池相关标准(CFF)建立国内本土化政策指南,以保证相关锂电池研究的可比性.
Life cycle assessment of LiCoO2 battery recycling for mobile phones
In order to assess the differences in environmental impact of the two recycling processes(pyrometallurgical and hydrometallurgical)and different allocation methods(EoL and CFF)for lithium cobalt oxide(LCO)batteries used in mobile phones,when considering the environmental benefits of the waste battery recycling and setting the functional unit to be the energy supply of 1 kWh from lithium cobalt oxide batteries,a cradle-to-grave life cycle assessment(LCA)was carried out for the LCO batteries,while the results were compared for the application of End-of-Life(EoL)and Circular Footprint Formula(CFF)allocation methods in the scenario of hydrometallurgical recycling process.The results indicated that the environmental benefits of hydrometallurgical recycling process were significantly greater than those of pyrometallurgical recycling process,which were about 2.89 times.Regarding Global Warming Potential and Fossil Resource Scarcity as well as three end points environmental damage indicators,the environmental benefits of EoL allocation were much lower than those of CFF allocation.The main reason was that the EoL allocation method counted all recycling benefits into the initial life cycle,compared to the CFF allocation method,which reasonably divided the environmental benefits of recycling into the life cycles of manufacturing recyclable materials and utilizing recycled materials according to the market situation.The CFF method proved to be more efficacious in mitigating the arbitrary disappearance of environmental impacts and avoiding the multi-counting of environmental benefits,which notably affected the accuracy of scientific quantification of environmental impacts,including the carbon emission assessment.It was also recommended to establish domestic localisation policy guidelines with reference to the lithium battery related standards(CFF)in the EU PEF to ensure the comparability of related lithium battery research.

lithium cobalt oxide batteryhydrometallurgypyrometallurgyenvironmental impact assessmentallocation method

彭喆、龚先政、杜世伟

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北京工业大学材料与科学学院,北京 100124

北京工业大学工业大数据应用技术国家工程实验室,北京 100124

钴酸锂电池 湿法冶金 火法冶金 环境影响评价 分配方法

国家重点研发计划资助项目

2022YFC3901701

2024

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2024.18(7)