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利用固体废弃物及污染土壤制备烧结砖和陶粒研究进展

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随着工业发展,我国固体废弃物的产生量不断增加,而固体废弃物的处理处置和资源化利用是当下面临的重要挑战.填埋作为处理固体废弃物的传统方法存在土地占用和污染等诸多问题.此外,我国存在大量的场地污染土壤,由于其修复成本高、处理技术不成熟,污染土壤的处理处置难题也引起了广泛关注.而污泥、粉煤灰和污染土壤等固体废弃物的主要成分为SiO2和Al2O3,利用其制备烧结砖和陶粒被认为是一种有效降低重金属危害和资源化利用的方法.在烧结过程中,矿物组分液化促进了重金属与铝硅酸盐之间的反应以及重金属价态的转换,使得重金属在砖块和陶粒中被有效固定.其固定方式包括形成稳定的矿物,被包裹在固体基质中,或转化为低迁移率的价态等.本研究总结了含重金属污染的污泥、粉煤灰、尾矿以及污染土壤等固体废弃物制备烧结砖和陶粒的研究进展,概括了制备烧结砖和陶粒的工艺流程及工艺条件,分析了影响重金属稳定化的因素,并对利用污染土壤等固体废弃物制备烧结砖和陶粒的可行性进行总结和展望.
Advancements in utilizing solid wastes and contaminated soils to prepare sintered brick and ceramic granules
The industrial development generates increasing solid wastes in China.While,it comes a big challenge to treatment or recycle these solid wastes.The traditional solid waste treatment methods as landfill encounters many problems such as occupying and contaminating the land.Besides,China has large quantities of contaminated soil in brown field.Due to high remediation cost and immaturity of the treatment technologies,the treatment of heavily contaminated soils also attracts widespread concern.Since the solid wastes such as sludge and fly ash as well as the contaminated soil contain the main contents of SiO2 and Al2O3,which can be used for preparing sintered brick and ceramic granule,this is considered to be an effective method of recycling to reduce the release of heavy metals.During the sintering process,the liquefaction of minerals promotes the reaction between heavy metals and aluminosilicates,meanwhile,changes the valence states of heavy metals,which results in effective immobilization of heavy metals in bricks and ceramic grains.The immobilization ways include the formation of stable minerals,encapsulation in a solid matrix,and conversion to low-mobility valence states.This study summarized the research progress on the preparation of sintered brick and ceramic granule from solid wastes(sludge,fly ash,tailings)and contaminated soils that contain heavy metal contamination,outlined the process flow and process conditions,analyzed the factors affecting the stabilization of heavy metals,and made the summarize and prospect for the feasibility of preparing sintered brick and ceramic granule from solid wastes such as contaminated soils.

sintered brickceramic granuleheavy metalsimmobilizationrecycling

范振辉、丁亮、夏威夷、金鑫、谷成、曲常胜

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南京大学环境学院,南京 210008

江苏省环保集团有限公司江苏省环境工程技术有限公司,江苏省生态环境保护地下水污染防治工程技术中心,南京 210036

南京师范大学环境学院,南京 210023

烧结砖 陶粒 重金属 固定化 资源化利用

2024

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2024.18(11)