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环境响应型智能膜及其在膜蒸馏中的研究进展

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膜蒸馏具有分离效率高、污染潜势低、操作简便等优势,在工业废水处理与资源化中具有显著优势.但膜污染和膜润湿问题仍悬而未决,限制其实际工程应用.环境响应型智能膜可感知外界环境条件变化后进而改变自身结构、特性与性能,故在膜法水处理领域极具应用潜力.该研究系统总结了 pH、温度、光、电场及磁场响应型智能膜的响应机制及在水处理中的研究进展,综述了智能膜在MD中应用的现状.结合环境响应机制与MD的特点,重点讨论了环境响应型智能膜在解决MD过程中存在的膜污染、膜润湿、低通量及长期稳定性差等问题的潜力,并对其在MD中应用的主要挑战及未来研究方向进行了展望.研究认为特殊润湿性智能膜的开发可为MD技术的发展与应用提供新方向,实现高效、稳定、简单、经济的智能膜的开发并明确其在MD过程机理,可推动MD技术的工业化应用.
Stimuli-responsive membrane and its research status in membrane distillation
Membrane distillation(MD)had proven its significant advantages in industrial wastewater treatment and reclamation for the high separation efficiency,low fouling potential,and convenient operation.However,membrane fouling and wetting issues remain unresolved,which limit the commercial application of MD.Stimuli-responsive membranes can respond to specific environmental stimulus and change their structure,characteristics,and performance correspondly,which has great potential in water and wastewater treatment based on membrane technologies.In this work,the responding mechanisms of the responsive membranes to stimuli in terms of pH,temperature,photo,electric field,and magnetic field and their research advancement in water and wastewater treatment were systematically reviewed,as well as their application status in MD.In view of the responding mechanism and the characteristic of MD process,the potentials of stimuli-responsive membranes in addressing membrane fouling and wetting issues,low permeability,and low long-term stability in MD were discussed.At last,a perspective and the challenges of stimuli-responsive membranes in MD application were analyzed.It was believed that the development of the membrane with the special wettability will be a new direction for MD development and application,the development of highly effective,stable,simple and cost-effective stimuli-responsive membrane and the understanding of the mechanism in MD had a potential in promoting the commercial application of MD.

membrane distillationstimuli-responsive membranesmembrane foulingmembrane wettingspecial wettability

郑利兵、高瑞、段宁鑫、苑宏英、员建、魏源送

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中国科学院生态环境研究中心,环境模拟与污染控制国家重点联合实验室,北京 100085

中国科学院生态环境研究中心,水污染控制实验室,北京 100085

Department of Chemical Engineering,KU Leuven,3001 Leuven,Belgium

天津城建大学环境与市政工程学院,天津 300384

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膜蒸馏 环境响应智能膜 膜污染 膜润湿 特殊润湿性

2024

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2024.18(11)