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典型煤气化场地土壤地下水DNAPLs识别及其分布特征

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判别污染场地土壤和地下水中是否存在DNAPLs,对于建立场地污染概念模型和筛选合适的修复技术具有重要意义.本研究以山西某关闭的煤气化厂为研究区,基于场地多期监测数据采用定量判别方法进行了判别,并分析了DNAPLs在土壤地下水中的分布特征.结果表明,该场地存在2个大的地下水DNAPLs污染源区,总面积2.25×104m2;土壤分层判别结果显示,DNAPLs出现在粉土层的点位数量最多,占42.3%,其次是杂填土层,占34.6%,中粗砂层占23.1%,表明DNAPLs更易于累积在粉土层中,并可穿透浅部粉土层继续向下迁移.通过空间关联分析发现,土壤DNAPLs分布范围已超出地下水DNAPLs源区,推测可能存在其它的地下水DNAPLs污染源区;场地包气带对DNAPLs迁移具有明显的阻滞作用,在污染较轻的地方,DNAPLs仅赋存在包气带中未能迁移至地下水,而在污染较重的地段,DNAPLs已穿透包气带进入地下水.建议该场地尽快开展土壤与地下水修复,防止污染物从DNAPLs持续释放形成更大面积的地下水污染羽.
DNAPLs identification and distribution in the soil and groundwater of a typical coal gasification site
It is significant to identify dense non-aqueous phase liquids(DNAPLs)in the soil and groundwater for the establishment of a conceptually contaminated site model and the selection of appropriate remediation techniques.In this study,a closed gas plant in Shanxi province was taken as a research site,DNAPLs were quantitatively discriminated based on the multi-period monitoring data,and their distributions were analyzed in the soil and groundwater.The results showed that DNAPLs are mainly derived from two groundwater regions with a total area of 2.25 × 104m2.Based on results of soil stratification discrimination,most DNAPLs sites existed in silt layer,which accounted for 42.3%of the total sample points,followed by those at miscellaneous fill layer(34.6%)and at medium coarse sand layer(23.1%).This implied that DNAPLs were more likely to accumulate in the silt layer and they could penetrate into the shallow silt layer even continue to migrate downwards.Through spatial correlation analysis,it was found that the distribution range of soil DNAPLs had exceeded the groundwater DNAPLs source zone,which proved the existence of other groundwater DNAPLs source zones.The DNAPLs migration was obviously retarded by the vadose zone.At the slightly polluted region,DNAPLs only existed in the vadose zone and failed to transfer into groundwater,whereas at the seriously polluted region,DNAPLs penetrated the vadose zone and entered groundwater.Therefore,it is proposed that soil and groundwater remediation should be carried out as soon as possible to prevent the continuous release of pollutants from DNAPLs and the formation of larger groundwater pollution plumes.

coal Gasification plantDNAPLs source zonevadose zonespatial distributionretardation

孟磊、冯启言、党晋华、李泽、戎艳青

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中国矿业大学物联网(感知矿山)研究中心,徐州 221008

中国矿业大学环境与测绘学院,徐州 221116

山西省生态环境监测和应急保障中心(山西省生态环境科学研究院),太原 030000

煤气化厂 DNAPLs源区 包气带 空间分布 阻滞作用

2024

环境工程学报
中国科学院生态环境研究中心

环境工程学报

CSTPCD北大核心
影响因子:0.804
ISSN:1673-9108
年,卷(期):2024.18(11)