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焚烧飞灰深度资源化技术进展及展望

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基于生活垃圾焚烧飞灰的产生方式及特性,探析了焚烧飞灰中无机氯盐回收处理技术、钙元素分离回收技术、重金属分离提取技术,分析各项技术存在的优缺点,并总结了 目前焚烧飞灰的最新资源化利用工业化进展。研究得出,被广泛认可的两套系统包括:低温二噁英解毒-水洗-含重金属盐水蒸发回收-钙组分用于水泥材料、高温烧结/熔融二嗯英解毒-盐及重金属挥发回收-钙组分形成陶粒或玻璃体。这些系统中二噁英均能得到有效处理;钙组分可资源化但是附加值不高,且钙资源化过程中需要关注重金属进入环境的总量所带来的长期环境风险;氯盐组分目前缺乏有成本效益的资源化途径。综上,未来需要在研发飞灰中钙及氯盐的有效资源化技术、出台更多细分技术的指导性文件作为理论支撑和设计依据方面进行深入研究。
Progress and Prospect of Deep Recycling Technology for Incineration Fly Ash
Based on the generation mode and characteristics of municipal solid waste incineration fly ash,the inorganic chloride salts recovery and treatment technologies,calcium element separation and recovery technologies,heavy metal elements separation and extraction technologies of incineration fly ash were explored.The advantages and disadvantages of each technology were analyzed,and the latest resource utilization industrialization progress of incineration fly ash were summarized.According to the study,two widely accepted systems were low-temperature dioxin detoxification+washing+evaporation recovery of heavy metal-containing salt water+calcium component forming cement,and high-temperature sintering/melting for dioxin detoxification+salt and heavy metal volatilization recovery+calcium component forming pottery/glass.In both systems,dioxins could be decomposed effectively.Calcium could be recycled,but the added value was not high,and in the process of calcium recycling,attention should be paid to the long-term environmental risks caused by the total amount of heavy metals entering the environment.There was currently a lack of cost-effective resourcing of chloride components.In the future,more investigations should be focused on developing effective recycling of calcium and chloride in fly ash,and need more detailed technical guidance documents as theoretical support and design basis.

incineration fly ashinorganic chloride saltsheavy metalscalciumrecycling

吕烨佳、张佳、岳阳、钱光人

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上海大学环境与化学工程学院,上海 200444

焚烧飞灰 无机氯盐 重金属 资源化

国家重点研发计划项目

2019YFC1906900

2024

环境卫生工程
天津市市容环境工程设计研究所

环境卫生工程

CSTPCD
影响因子:0.279
ISSN:1005-8206
年,卷(期):2024.32(4)