首页|贵州百地金矿床石英微量元素和H-O同位素地球化学特征及其矿床成因意义

贵州百地金矿床石英微量元素和H-O同位素地球化学特征及其矿床成因意义

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贵州百地金矿床位于右江盆地中部,是以细碎屑岩为赋矿围岩、受陡倾斜断褶带构造系统控制的典型中型金锑共生矿床.本文以该矿床各热液阶段石英为研究对象,分析其微量、稀土元素含量和H-O同位素特征,探讨成矿流体来源及其演化过程.结果显示:各阶段石英均富集Sb、As、Cd、Ge、W、Li,强烈亏损Be、Nb、Zr、Hf;各阶段石英稀土含量及配分曲线差别较大:Ⅰ阶段石英稀土配分曲线呈较明显右倾,LREE富集,Ce异常不明显,具弱Eu负异常;Ⅱ阶段石英稀土配分曲线呈较平缓右倾,Ce和Eu异常不明显;Ⅲ阶段稀土配分曲线呈"上凸型",MREE富集,具有微弱Ce正异常和明显Eu正异常.研究表明:成矿流体具有明显的混合成因,为以地层建造水为主,含少量深部岩浆流体与基底变质水的混合流体;Ⅰ阶段流体具还原、酸性特征;Ⅱ阶段流体继承了 Ⅰ阶段流体特征,环境向氧化、碱性转变,使Au等元素发生沉淀,REE和Y进入Ⅲ阶段流体;Ⅲ阶段流体处于氧化、碱性环境,造成Sb的沉淀和围岩Sr等元素的进入;Ⅱ阶段到Ⅲ阶段流体环境转变和深部基底变质水减少,说明百地金矿床热液成矿作用是多期次的,深部岩浆流体和基底变质水在成矿流体中的参与度随成矿过程的演进而逐渐降低.
Geochemical Characteristics and Genetic Indications of Trace Elements and H-O Isotopes in Quartz of Baidi Gold Deposit,Guizhou Province
The Baidi gold deposit of Guizhou Province is a typical gold-antimony co-occurrence medium deposit located in the middle of Youjiang Basin,with fine clastic rock as its host rock and controlled by the tectonic system of steep inclined fault-fold belt.In this paper,the contents of trace and rare earth elements and H-O isotope of quartz in different hydrothermal mineralization stages are tested and analyzed,and the source and evolution of ore-forming fluid are discussed.The results show that quartz from at each hydrothermal mineralization stage,Sb,As,Cd,Ge,W,Li are enriched,and Be,Nb,Zr,Hf are strongly depleted,the rare earth content and partition curves of quartz from different hydrothermal mineralization stages vary greatly,the rare earth content and partition curve from quartz in different stages are quite different.The first hydrothermal mineralization stage is more obvious to the right,LREE is enriched,Ce anomaly is not obvious,and Eu negative anomaly is weak.The rare earth partition curve from quartz in the second hydrothermal mineralization stage is gently to the right,and the Ce and Eu anomalies are not obvious.The rare earth partition curve from quartz in the third hydrothermal mineralization stage is"upconvex",with MREE enrichment,weak positive Ce anomaly and obvious positive Eu anomaly.The results show that the ore-forming fluid of Baidi gold deposit has obvious mixed origin,mainly composed of formation water and a small amount of deep magmatic fluid mixed with basement metamorphic water.The fluid environment in theⅠ stage is reductive and acidic.The Ⅱ stage fluid inherited the characteristics of the Ⅰ stage fluid,and the environment changed to oxidation,alkaline,so that Au and other elements precipitated,and REE and Y entered the Ⅲ stage fluid.In the Ⅲ stage,the fluid environment is oxidized and alkaline,resulting in the precipitation of Sb and the entry of surrounding rock Sr.From stage Ⅱ to stage Ⅲ,the changes of fluid environment and the reduction of metamorphic water in deep basement indicate that the hydrothermal mineralization process of Baidi gold deposit is multi-stage,and the participation of deep magmatic fluid and basement metamorphic water in the ore-forming fluid gradually decreases.

quartztrace elementsrare earth elementssource and evolution of ore-forming fluidgeochemical characteristicsBaidi gold deposit,Guizhou Province

吴波、吴治君、赵明峰、彭慈刚、斯恩智、周克林、杨恩林、潘有良、陆建宝

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贵州省地质矿产勘查开发局117地质大队,贵州贵阳 550018

中国科学院地球化学研究所,贵州贵阳 550081

贵州师范大学,贵州贵阳 550025

石英 微量元素 稀土元素 地球化学特征 成矿流体来源及演化 贵州百地金矿床

2024

华南地质
武汉地质矿产研究所

华南地质

影响因子:0.516
ISSN:1007-3701
年,卷(期):2024.40(4)