湖北理工学院学报2025,Vol.41Issue(1) :65-71.DOI:10.3969/j.issn.2095-4565.2025.01.012

2D TiO2/ZnO的合成及光催化活性

Synthesis and Photocatalytic Activity of 2D TiO2/ZnO

范艳玲 任咏琪 徐玉林
湖北理工学院学报2025,Vol.41Issue(1) :65-71.DOI:10.3969/j.issn.2095-4565.2025.01.012

2D TiO2/ZnO的合成及光催化活性

Synthesis and Photocatalytic Activity of 2D TiO2/ZnO

范艳玲 1任咏琪 1徐玉林1
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作者信息

  • 1. 湖北理工学院 化学与化工学院,湖北 黄石 435003
  • 折叠

摘要

摘 要:光催化技术具有降解速率高、无毒、成本低等特点,在抗生素废水处理方面具有良好的应用前景.文章采用水热法合成2D TiO2/ZnO复合氧化物光催化剂,通过降解盐酸四环素(TCH)评价了其光催化活性,并探究了TiO2 负载量、煅烧温度、煅烧时间和盐酸四环素用量对光催化活性的影响.结果表明:与2D TiO2 和2D ZnO相比,2D TiO2/ZnO-50 具有更好的催化活性,在煅烧温度为300℃,煅烧时间为2h的条件下,在可见光下对5 mg/L TCH的降解率可达93.0%,对20 mg/L的盐酸四环素的降解率为82.2%.在 2D TiO2/ZnO-50 浓度为 200 mg/L,盐酸四环素浓度为 20 mg/L 时,2D TiO2/ZnO-50 光催化降解盐酸四环素属于准一级动力学反应,速率常数为0.009 09 min-1,半衰期为76.2 min.

Abstract

Photocatalytic technology has a good application prospect in wastewater containing antibiotics treat-ment because of its high degradation rate,non-toxicity and low cost.2D TiO2/ZnO composite photocata-lysts were synthesized by hydrothermal method.The photocatalytic activity of the constructed catalyst was e-valuated by photocatalytic degradation of tetracycline hydrochloride(TCH).The effects of TiO2 loads,calci-nation temperature,calcination time and tetracycline hydrochloride dosage on the photocatalytic activity of 2D TiO2/ZnO were investigated.The experimental results showed that 2D TiO2/ZnO-50 exhibited improved catalytic activity compared with pure 2D TiO2 or 2D ZnO.When using 2D TiO2/ZnO-50 calcinated at 300℃for 2 h,the degradation rates of TCH of 5 mg/L and 20 mg/L under visible light were 93.0%and 82.2%,respectively.The reaction of photocatalytic degradation TCH(20 mg/L)by2D TiO2/ZnO-50(200 mg/L)can be expressed as pseudo-first-order kinetic model,with a rate constant of 0.009 09 min-1 and a half-life of 76.2 min.

关键词

2D/TiO2/ZnO/可见光催化/水热法/盐酸四环素

Key words

2D TiO2/ZnO/visible light catalysis/hydrothermal method/tetracycline hydrochloride

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出版年

2025
湖北理工学院学报
湖北理工学院

湖北理工学院学报

影响因子:0.434
ISSN:2095-4565
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