首页|复配絮凝处理高浓度含盐原油罐切水的研究

复配絮凝处理高浓度含盐原油罐切水的研究

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采用不同类型絮凝剂聚合[聚合氯化铝(PAC)、聚合硫酸铁(PFS)和聚丙烯酰胺(PAM)]处理高浓度含盐原油罐切水,探索絮凝剂投量浓度、搅拌速度、pH值和投加时间间隔对絮凝效果的影响.结果表明:复配使用絮凝剂聚合氯化铝与阳离子型聚丙烯酰胺(CPAM)处理高浓度含盐原油罐切水的絮凝效果更佳.絮凝剂的投量浓度、絮凝搅拌速度、pH值和投加间隔时间均影响絮凝的效果,其中絮凝剂的用量影响最大.较为适宜的絮凝条件:pH值为6~11,PAC投量浓度为400 mg/L且混合搅拌速度为200 r/min,CPAM投量浓度为1.0 mg/L且混合搅拌速度为 100 r/min,2 种絮凝剂的投加间隔为60 min.絮凝对浊度的去除率高达98.7%,固体悬浮物(SS)的去除率高达 96.5%,废水中的石油类含量从 0.339 mg/L降到 0.115 mg/L,废水的氨氮、化学需氧量(COD)以及254 nm波长紫外光下的吸光度(UV254)的去除率分别达到55.0%,36.6%和20.4%,最终絮凝出水的总铁含量从41.85 mg/L降到 5.42 mg/L.
Study on the Treatment of Crude Oil Tank Cut Water with High Concentration of Saline by Composite Flocculation
Different types of flocculants polyaluminum chloride(PAC),polymerized ferric sulfate(PFS)and polyacrylamide(PAM)were used to treat the effluent of high-concentration salty crude oil tanks to explore the effects of flocculant dosage,stirring speed,pH and dosage time interval on flocculation effect.The effect was better when flocculant PAC and cationic polyacrylamide(CPAM)were used to treat the discharged wastewater of high-concentration salty crude oil tanks.The dosage of flocculant,flocculation stirring speed,pH and dosing interval have a certain influence on the effect of flocculation,among which the dosage of flocculant has the greatest influence.It showed better flocculation effect under the conditions of pH range of 6-11,PAC dosage of 400 mg/L,mixing and stirring speed of 200 r/min,CPAM dosage of 1.0 mg/L and mixing and stirring speed of 100 r/min,and the dosing interval of the two flocculants is 60 min.The removal rate of turbidity by flocculation was as high as 98.7%,the removal rate of solid suspended solids(SS)was noted about 96.5%,the petroleum content in wastewater decreased from 0.339 mg/L to 0.115 mg/L,the removal rate of ammonia nitrogen,chemical oxygen demand(COD)and absorbance at 254 nm UV light(UV254)in wastewater reached 55.0%,36.6%and 20.4%,respectively,and the total iron content of the final condensed water reduced from 41.85 mg/L to 5.42 mg/L.

discharged wastewater of crude oil tankshigh-concentrationsaltyturbidityflocculation

李森、李雪文、周晴、周晓龙

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上海化工研究院有限公司,上海 200062

华东理工大学绿色能源化工国际联合研究中心,上海 200237

原油罐切水 高浓度 含盐 浊度 絮凝

上海市优秀技术带头人项目

22XD1431800

2024

化学反应工程与工艺
联合化学反应工程研究所 ,中石化上海石油化工研究院

化学反应工程与工艺

CSTPCD
影响因子:0.392
ISSN:1001-7631
年,卷(期):2024.40(2)
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