首页|苹果酸辅助NH2-MIL-125(Ti)合成及其光催化性能研究

苹果酸辅助NH2-MIL-125(Ti)合成及其光催化性能研究

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以苹果酸为添加剂辅助合成了NH2-MIL-125(Ti)光催化剂,采用X射线衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外光谱(FT-IR)、紫外可见漫反射光谱(UV-vis)、光致发光光谱(PL)等手段对其进行了表征,并以光催化降解罗丹明B(RhB)反应为探针评价其性能.结果表明:少量添加苹果酸使得NH2-MIL-125(Ti)晶体厚度变薄、尺寸变小;而大量添加时,NH2-MIL-125(Ti)晶体尺寸变大,同时晶体错位生长,缺陷增加,提高了电子空穴分离效率和界面电荷传输效率,促进样品光降解性能,提升光催化活性,反应 120 min后RhB的移除率达到83%.
NH2-MIL-125(Ti)Synthesized with Malic Acid Additive and Its Photocatalytic Performance
NH2-MIL-125(Ti)samples were synthesized with malic acid as an additive,which were characterized by X-ray diffraction(XRD),scanning electron microscope(SEM),Fourier transform infrared spectroscopy(FT-IR),ultraviolet visible spectrophotometry(UV-vis)and photoluminescence spectroscopy(PL).The photocatalytic performance of the samples was evaluated by photocatalytic degradation reaction of Rhodamine B(RhB).The results showed that a small amount of malic acid addition made the NH2-MIL-125(Ti)crystals thinner and smaller,while a large amount of malic acid addition made the NH2-MIL-125(Ti)crystals larger,possesses more mesopores,improved electron hole separation efficiency and interfacial charged transport efficiency,which promoted the photodegradation performance of the samples.As a result,the photocatalytic activity was improved and the removal of RhB reached 83% in 120 min.

NH2-MIL-125(Ti)additivemorphological controldye degradation

刘民、马作启、郭新闻

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大连理工大学化工学院催化化学与工程系,辽宁 大连 116024

NH2-MIL-125(Ti) 添加剂 形貌调控 染料降解

2024

化学反应工程与工艺
联合化学反应工程研究所 ,中石化上海石油化工研究院

化学反应工程与工艺

CSTPCD
影响因子:0.392
ISSN:1001-7631
年,卷(期):2024.40(3)
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