首页|基于中空纤维膜接触器的氨水吸收CO2的膜润湿性能模拟研究

基于中空纤维膜接触器的氨水吸收CO2的膜润湿性能模拟研究

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膜接触器吸收(膜吸收)技术结合了膜分离与气体吸收的优点,在碳捕集技术中应用潜力巨大,但膜润湿是制约其发展和应用的主要障碍之一.着重研究了基于中空纤维膜接触器的氨水吸收CO2过程中的膜润湿问题.本工作通过引入润湿分数的概念,利用 COMSOL建立了润湿状态的二维稳态非润湿膜吸收模型,考察了不同操作参数下膜润湿对CO2吸收性能的影响.结果显示膜润湿对传质性能具有显著的影响,完全润湿条件下的CO2脱除效率和传质速率相比非润湿条件分别下降了 38.5%和 32.5%;气相参数的变化对非润湿状态的影响更大,而液相参数则对润湿状态的影响更明显.
Membrane Wetting Performance Simulation Study of Ammonia Water Absorption of CO2 Based on Hollow Fiber Membrane Contactor
The membrane contactor absorption(membrane absorption)technology combines the advantages of membrane separation and gas absorption,exhibiting significant potential in carbon capture technology.However,membrane wetting is a significant obstacle restricting its development and application.The wetting of the membrane in the process of CO2 absorption by ammonia water based on hollow fiber membrane contactor is emphatically studied.In this paper,by introducing the concept of wetting fraction,a two-dimensional stable non-wetting membrane absorption model was established by COMSOL,and the influence of membrane wetting on the CO2 absorption performance under different operating parameters was investigated.The results indicate that membrane wetting significantly affects mass transfer performance,with CO2 removal efficiency and mass transfer rate decreasing by 38.5%and 32.5%,respectively,under fully wetted conditions compared to non-wetted conditions.Changes in gas phase parameters have a greater impact on the non-wetted state,while liquid phase parameters have a more pronounced effect on the wetted state.

carbon captureammoniahollow fiber membrane contactormembrane wettingnumerical simulation

张志恒、牟小轩、李深奥、夏杰成、竺新波、王甫

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宁波大学海运学院,浙江 宁波 315800

碳捕集 氨水 中空纤维膜接触器 膜润湿 数值模拟

国家自然科学基金面上项目

52276010

2024

化学反应工程与工艺
联合化学反应工程研究所 ,中石化上海石油化工研究院

化学反应工程与工艺

CSTPCD
影响因子:0.392
ISSN:1001-7631
年,卷(期):2024.40(4)
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