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电工膜用高纯聚丙烯脱灰技术研究

Deashing technology of high purity polypropylene for electrical film

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开发低灰分聚丙烯专用料、突破国外"卡脖子"技术,对于我国BOPP薄膜行业乃至整个电力电容器产业都具有重要意义.设计了"己烷+乙酰乙酸乙酯"双组分复配洗涤溶剂体系,针对本身灰分含量较低的聚丙烯树脂进行深度洗涤脱灰处理,进一步降低ZN催化剂体系下残余在聚丙烯内的残余的Ti、Mg和Al元素,得到了低于20 μg·g-1的聚丙烯粉料,灰分脱除率可达70%以上.针对洗涤剂种类、洗涤时间、洗涤温度和洗涤配比等工艺进行了系统研究,对聚丙烯产品的理化性能和电气性能等进行表征.结果表明洗涤前后的薄膜击穿强度从562.3提升至632.8 kV·mm-1,电导率从 2.0×10-11降低至 1.0×10-11 S·m-1.
It is of great significance for China's BOPP film industry and even the whole power capacitor industry to develop the ultra-low ash polypropylene material and break through the"Strangle"technology abroad.In this study,a"hexane+ethyl acetoacetate"two-component composite washing solvent system was designed,and the polypropylene resin with low ash content was subjected to deep washing and deash-ing treatment,the content of Ti,Mg and Al in PP was further reduced,and the ash removal rate of PP powder was over 70%,which was lower than 20 μg·g-1.The influence of detergent types,washing time,washing temperature and washing ratio were studied,and the physical and chemical properties and elec-trical properties of polypropylene were characterized.The results showed that the film breakdown strength increased from 562.3 to 632.8 kV·mm-1 and the conductivity decreased from 2.0×10-11 to 1.0×10-11 S·m-1 before and after washing.

polypropyleneresinashBOPP filmcapacitordewashing

周昌浩、邢照亮、姜涛、李健

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天津科技大学化工与材料学院,天津 300457

全球能源互联网研究院有限公司先进输电技术国家重点研究室,北京 102200

聚丙烯 树脂 灰分 BOPP薄膜 电容器 脱灰

2024

化学工业与工程
天津化工学会 天津大学

化学工业与工程

CSTPCD北大核心
影响因子:0.406
ISSN:1004-9533
年,卷(期):2024.41(1)
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