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BGL气化炉除CH4的操作模拟研究

Mathematical modeling of CH4 elimination for BGL gasifier

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氮肥行业中BGL气化技术应用前景好,但该技术生产的合成气中CH4含量较高,无法满足合成氨原料要求.本研究充分考虑气化反应特性,拟在BGL气化炉设第二喷嘴,通过二次补燃的方式去除CH4.进而,在已建立的新型BGL气化炉模型基础上,探究了二次补燃去除合成气中CH4的效果.研究表明:补燃剂进料量为第一喷嘴进料量的25%时,出口气体中CH4含量降至1%以下,且碳转化率大于99%.通过提高第一喷嘴进料蒸气比例可获得用于合成氨生产的高氢碳比合成气.
BGL gasification technology is promising in the nitrogen fertilizer industry.However,the syn-gas containing excessive CH4 produced by the BGL gasification cannot satisfy the demand for the synthetic ammonia process.In this work,a second nozzle was set in the BGL gasifier to eliminate CH4 via seconda-ry combustion.Then,the effect of secondary combustion was analyzed based on the proposed BGL gasifi-er model.It was found that the CH4 concentration was less than 1%and the char conversion was higher than 99%when the gasifying agent of the second nozzle was 25%of that of the first nozzle.The syngas with high H/C used for the synthetic ammonia process can be produced by increasing the steam propor-tion in the first nozzle.

BGL gasifiersecondary combustionmathematical modeling

张权聪、薛康、曹志凯、周华

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厦门大学化学化工学院,化学工程与生物工程系,福建厦门 361005

西安航天源动力工程有限公司,西安 710100

BGL气化炉 二次补燃 数学建模

国家自然科学基金

21576228

2024

化学工业与工程
天津化工学会 天津大学

化学工业与工程

CSTPCD北大核心
影响因子:0.406
ISSN:1004-9533
年,卷(期):2024.41(1)
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