首页|IBOMA-MPEGA-DMAM共聚物的合成及其对酞菁蓝水性色浆的分散研究

IBOMA-MPEGA-DMAM共聚物的合成及其对酞菁蓝水性色浆的分散研究

Synthesis of IBOMA-MPEGA-DMAM copolymer and its dispersion in phthalocyanine blue aqueous colorant

扫码查看
以甲基丙烯酸异冰片酯(IBOMA)、聚乙二醇单甲醚丙烯酸酯(MPEGA)、N,N二甲基丙烯酰胺(DMAM)为单体,偶氮二异丁腈(AIBN)作引发剂,采用溶液自由聚合得到三元共聚物P(IBO-MA-MPEGA-DMAM),并将其用于制备水性酞菁蓝色浆的分散体系.以色浆黏度为评价指标,通过中心复合法优化引发剂用量、反应温度和反应时间;采用FT-IR、1H NMRGPC表征聚合物的化学结构和相对分子质量,并通过对水性酞菁蓝浆料的粒径、微观形貌、离心及冻融稳定性进行分析,考察了分散剂对酞菁蓝分散性影响.结果表明:当引发剂用量为2.12%,反应温度为81 ℃,反应时间5.3 h时分散性能较好且当分散剂用量3.6%时,浆料黏度为6.2 mPa·s,平均粒径为205 nm,与未添加分散剂、市售分散剂相比,用P(IBOMA-MPEGA-DMAM)分散剂制得的酞菁蓝浆料具有较好的分散稳定性.
The terpolymer of P(IBOMA-MPEGA-DMAM)was obtained by solution free polymerization through free solution polymerization of isobornyl methacrylate(IBOMA),polyethylene glycol monomethyl ether acrylate(MPEGA)and,N,N-dimethacrylamide(DMAM),with azobisisobutyronitrile(AIBN)as initiator,and the terpolymer was applied to the aqueous phthalocyanine blue dispersion system.Taking the color paste viscosity as a main measurement index,the effects of the dosage of initiator,reaction tem-perature and reaction time on the dispersibility were optimized by central composite method.FT-IR and 1H NMRGPC were used to characterize the chemical structure and molecular weight of polymers of the polymer.The particle size,microstructure,centrifugal and freeze-thaw stability of the aqueous phthalocy-anine blue slurry were analyzed,and the influence of the dispersant on the dispersion of phthalocyanine blue was investigated.The results show that when the dosage amount of initiator is 2.12%,the reaction temperature is 81 ℃,the reaction time is 5.3 h,the dispersion performance is good,and when the a-mount of dispersant is 3.6%,the viscosity of the slurry is 6.2 mPa·s and the average particle size is 205 nm.Compared with commercial dispersants without added dispersants,the phthalocyanine blue slurry prepared by P(IBOMA-MPEGA-DMAM)has better dispersion stability.

hyperdispersantsynthesiscentral composite designdispersion stabilityphthalocyanine blue

蒋双双、印晓刚、毛连山

展开 >

南京林业大学化学工程学院,南京 210037

超分散剂 合成 中心复合设计 分散稳定性 酞菁蓝

2024

化学工业与工程
天津化工学会 天津大学

化学工业与工程

CSTPCD北大核心
影响因子:0.406
ISSN:1004-9533
年,卷(期):2024.41(3)
  • 20