首页|α-Fe2O3/还原氧化石墨烯(RGO)的制备及应用

α-Fe2O3/还原氧化石墨烯(RGO)的制备及应用

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为实现非对称超级电容器(ASC)的高电化学性能,以FeCl3·6H2O为铁源,通过水热法将α-Fe2O3纳米颗粒均匀分散在还原的氧化石墨烯(RGO)薄片上,成功制备α-Fe2O3/RGO复合材料.该复合材料采用SEM、TEM、XRD和XPS进行表征,并利用标准三电极体系进行电化学性能测试.结果显示:高度组装的α-Fe2O3/RGO在1 A·g-1下具有740.8F·g-1的大比电容,并且于5 A·g-1下实现80.0%的长循环稳定性(10 000圈).以制备的α-Fe2O3/RGO为负极,NiCo2O4为正极组装了 NiCo2O4//α-Fe2O3/RGO非对称超级电容器,不仅在792.8 W·kg-1下获得47.8 Wh·kg-1的能量密度,而且在5 A·g-1下仍然维持78.6%的循环稳定性(10 000圈).这极大地促进了 ASC在储能系统的应用.
Preparation and application of α-Fe2O3/reduced graphene oxide(RGO)
The α-Fe2O3/RGO composite with α-Fe2O3 nanoparticles(FeCl3·6H2O as the iron source)uniformly dispersed on reduced graphene oxide(RGO)flakes was successfully prepared by a hydrother-mal method to achieve high electrochemical performance of asymmetric supercapacitors(ASCs).It was characterized by SEM,TEM,XRD,and XPS.And electrochemical properties were tested using a stand-ard three-electrode system.The results show that the highly assembled α-Fe2O3/RGO has a large specific capacitance of 740.8 F·g-1 at 1 A·g-1 and a long cycle stability of 80.0%(10 000 cycles)at 5 A·g-1.The NiCo2O4//α-Fe2O3/RGO asymmetric supercapacitor was assembled with the prepared α-Fe2O3/RGO as the negative electrode and NiCo2O4 as the positive electrode.The energy density of 47.8 Wh·kg-1 was obtained at 792.8 W·kg-1,and 78.6%cyclic stability(10 000 cycles)was maintained at 5 A·g-1.This greatly promotes the application of ASCs in energy storage systems.

α-Fe2O3grapheneasymmetric supercapacitorcycle performance

王宏智、包赛赛、苏展、于金山、张卫国

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天津大学化工学院,天津 300072

国网天津市电力公司电力科学研究院,天津 300384

天津市电力物联网企业重点实验室,天津 300384

天津体育学院,天津 301617

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α-Fe2O3 石墨烯 非对称超级电容器 循环性能

2025

化学工业与工程
天津化工学会 天津大学

化学工业与工程

北大核心
影响因子:0.406
ISSN:1004-9533
年,卷(期):2025.42(1)