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化学反应方向和反应条件的学科理解

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人教版(2019)化学教材关于化学反应方向有化学热力学角度和热力学第二定律角度的2种表述,文章对2种表述进行了学科理解,分析了学生学习的易混淆点,提出了教材编写建议.从热力学角度分析了可逆反应正、逆反应方向都可以自发的原因.从热力学角度、动力学角度对化学反应条件进行了学科理解,提出了化学反应条件有热力学条件、动力学条件和反应调控的条件.通过Fe与O2反应、Na与O2反应、1,3-丁二烯的加成反应等例子分析了反应条件与反应产物的关系以及如何调控反应条件影响反应产物.提出了化学反应方向和反应条件的教学建议以及教师学科理解的建议.
Discipline Understanding of Chemical Reaction Direction and Reaction Conditions
The chemistry textbook of the People's Education Press(2019)has two expres-sions about the direction of chemical reactions:the perspective of chemical thermodynamics and the perspective of the second law of thermodynamics.The article provides a disciplinary under-standing of the two expressions,analyzes the confusing points that students may have,and pro-poses suggestions for textbook writing.The reason why reversible reactions can occur spontane-ously in both forward and reverse directions is analyzed from a thermodynamic perspective,and the chemical reaction conditions include thermodynamic conditions,kinetic conditions,and reac-tion regulation conditions.A disciplinary understanding of chemical reaction conditions from the perspectives of thermodynamics and kinetics has been gained,and through examples such as Fe and O2 reactions,Na and O2 reactions,and 1,3-butadiene addition reactions,the relationship between reaction conditions and reaction products has been analyzed,as well as how to regulate the influence of reaction conditions on reaction products.Teaching suggestions for the direction and conditions of chemical reactions have been proposed,as well as suggestions for teachers'dis-ciplinary understanding.

spontaneityreaction directionreaction conditionsreaction regulationdisci-pline understanding

叶礼华、张军

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重庆市巴蜀中学校 重庆 400013

西南大学教师教育学院 重庆 400715

自发性 反应方向 反应条件 反应调控 学科理解

2025

化学教育
中国化学会

化学教育

北大核心
影响因子:0.711
ISSN:1003-3807
年,卷(期):2025.46(1)