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12C16O2分子位于1.57 μm的饱和吸收光谱

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本文展示了基于光梳锁频-光腔衰荡光谱装置测量的12C16O2分子位于1.57 μm附近的30012←00001振动带中转动量子数最高为68的共计37根振转跃迁的饱和吸收光谱,其频率确定至kHz水平;文献和CDSD2019数据库中的多普勒光谱确定的30012振动态的振转能级与本工作确定的数值存在超过1 MHz的偏差.
Saturated Cavity Ring-Down Spectroscopy of 12C16O2 near 1.57 μm
We present the saturated absorption spectroscopy of the 30012←00001 band of 12C16O2 by a comb-locked cav-ity ring-down spectrometer near 1.57 μm.Positions of 37 lines with rota-tional quantum numbers up to 68 were determined with an accuracy of a few kHz.Comparisons of the ro-vibrational energy levels determined in this work with the Doppler-limited experimental values from literature and those from the CDSD2019 databank are given.De-viations exceeding 1 MHz were observed in the transitions blended by other carbon dioxide isotopologues.

Saturated absorption spectroscopyCavity ring-down spectroscopy12C16O2High precision

江山、谈艳、刘安雯、周晓国、胡水明

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中国科学技术大学化学物理系,合肥 230026

饱和吸收光谱 光腔衰荡光谱 12C16O2 高精密

国家自然科学基金国家自然科学基金国家自然科学基金Ministry of Science and Technology of China

2227309341905018219030802022YFF 0606500

2024

化学物理学报(英文版)
中国物理学会

化学物理学报(英文版)

CSTPCDEI
影响因子:0.162
ISSN:1674-0068
年,卷(期):2024.37(1)