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高厚径比印刷线路板环氧树脂塞孔油墨的制备及应用

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为了实现高厚径比印刷线路板(PCB)树脂塞孔的同时并保证油墨的性能,本文以环氧树脂为基体,改性后的微米/纳米SiO2为填料,搭配固化剂甲基六氢苯酐和其他助剂在特定工艺条件下制成塞孔油墨。利用差示扫描量热法(DSC)确定油墨的固化工艺参数;红外光谱(FT-IR)对改性前后的SiO2进行表征分析;通过热膨胀测试(CTE)、拉伸强度测试、树脂塞孔测试,研究不同粒径填料添加比例对油墨性能的影响,确定油墨的最佳配方。结果表明:本实验制备的W/N70-30油墨的热膨胀系数和拉伸强度比油墨产品PHP-3F-DS和PHP-900好;塞孔后发现5 mm的PCB板上0。13 mm和0。15 mm孔径的通孔背面都呈现出油现象,其塞孔效果最好,因此本实验制备的W/N70-30油墨能够应用于高厚径比(40∶1)印刷线路板。
Preparation and application of epoxy resin plug hole ink for printed circuit board with high thickness-diameter ratio
In order to achieve high aspect ratio of printed circuit board(PCB)resin plug hole and ensure the performance of the ink at the same time,this paper uses epoxy resin as the matrix,modified micron/nano SiO2 as the filler,with curing agent methyl hexa-hydrophthalic anhydride and other additives under certain process conditions to make plug hole ink.The curing process parameters of ink were determined by differential scanning calorimetry(DSC).Infrared spectroscopy(FT-IR)was used to characterize the SiO2 before and after modification.Through thermal expansion test(CTE),tensile strength test and resin plug hole test,the influence of different particle size filler addition ratio on ink performance was studied,and the optimal formula of ink was determined.The results show that the thermal expansion coefficient and tensile strength of W/N70-30 ink prepared in this experiment are better than those of PHP-3F-DS and PHP-900 ink products.After plugging the hole,it was found that the back of the through-holes with 0.13 mm and 0.15 mm apertures on the 5 mm PCB board showed oil phenomenon,and the plugging effect was the best.Therefore,the W/N70-30 ink prepared in this experiment can be applied to high thickness ratio(40∶1)printed circuit boards.

silicon dioxideepoxy resin inkcoefficient of thermal expansiontensile strengthresin plug hole

凌中阳、刘湘龙、张大为、闫美玲、甘娈娈、徐子晨、万里鹰

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南昌航空大学材料科学与工程学院,江西 南昌 330063

广州兴森快捷电路科技有限公司,广东 广州 510063

中材科技(萍乡)风电叶片有限公司,江西 萍乡 337200

二氧化硅 塞孔油墨 热膨胀系数 拉伸强度 树脂塞孔

2025

化学研究与应用
四川省化学化工学会 四川大学

化学研究与应用

北大核心
影响因子:0.555
ISSN:1004-1656
年,卷(期):2025.37(1)