首页|兰州百合中22种无机元素与种植区域相关性的研究

兰州百合中22种无机元素与种植区域相关性的研究

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目的 研究兰州百合中22种无机元素与种植区域的相关性.方法 用超级微波消解仪处理样品,采用电感耦合等离子体质谱仪测定兰州百合中22种无机元素的含量;对所得数据进行主成分分析,筛选特征元素,并对特征元素与种植区域的相关性进行系统聚类分析.结果 22种无机元素的线性关系良好,均r≥0.9967;定量限为6.5×10-3～26.3517μg·L-1,检出限为2.1×10-3～8.5071μg·L-1;精密度、重复性、稳定性试验的RSD均小于6.82％;平均加样回收率为80.1％～128.8％,RSD为1.81％～6.12％(n=9).锰、铝、钾、钒、铁、铜、钡、镁、锂、锶、镓等为兰州百合的特征元素,其含量水平根据种植区域不同聚为3类.结论 所用方法操作简便、灵敏度高,为兰州百合的地理标志保护和利用提供了依据.
Study on the correlation between the 22 kinds of inorganic elements in Lilium davidii and its planting regions
OBJECTIVE To explore the correlation between 22 inorganic elements in Lilium davidii and its planting regions in Lanzhou.METHODS Samples were digested by super microwave digestion,the contents of 22 kinds of inorganic elements were determined by inductively coupled plasma mass spectrometry,the principal components analysis(PCA)was performed on the data,the characteristic elements were screened,and the correlation between the characteristic elements and planting regions was systematically clustered.RESULTS The linear relationship of 22 inorganic elements was good with r≥0.9967,the limits of quantification were 6.5 × 10-3-26.3517 μg·L-1,the limits of detection were 2.1 × 10-3-8.5071 μg·L-1.RSDs of precision,stability and repeatability tests were all less than 6.82％,and the average recoveries were 80.1％-128.8％,RSD range from 1.81％to 6.12％(n=9).55Mn,27Al,39K,51V,56Fe,63Cu,137Ba,24Mg,7Li,88Sr and 69Ga were the characteristic elements of L.davidii,and the content of characteristic elements was clustered into three categories according to different planting regions.CONCLUSION This method is simple and sensitive,and can provide reference for the protection and utilization of geographical indications of L.davidii.

Lilium davidiiPlanting areaInductively coupled plasma mass spectrometryInorganic elementsPrincipal component analysisCharacteristic elementsClustering analysisCorrelation

朱仁愿、孙谏、王行智、陈婷、邱国玉

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兰州市食品药品检验检测研究院国家市场监管食品中农药兽药残留监控重点实验室甘肃省种植中药材外源性污染物监测工程研究中心,甘肃兰州 730050

甘肃药业集团科技创新研究院有限公司,甘肃兰州 730050

兰州百合 种植区域 电感耦合等离子体质谱法 无机元素 主成分分析 特征元素 聚类分析 相关性

国家市场监督管理总局科技计划项目甘肃省科技重大专项-企业创新联合体项目甘肃省市场监督管理局科研项目甘肃省市场监督管理局科研项目甘肃省药品监督管理局科研项目

2023MK12022ZD6FA021-3SSCJG-SP-A202205SSCJG-J2023032022GSMPA0067

2024

10.13375/j.cnki.wcjps.2024.05.013

华西药学杂志
四川大学,四川省药学会

华西药学杂志

CSTPCD北大核心
影响因子：0.624
ISSN：1006-0103
年,卷(期)：2024.39(5)