舰船科学技术2024,Vol.46Issue(3) :75-78.DOI:10.3404/j.issn.1672-7649.2024.03.013

船用铸铁耐高温甲酸腐蚀涂层抗高温腐蚀性能研究

Research on the high-temperature corrosion resistance of formic acid corrosion resistant coatings on cast iron used in ships

刘昭亮 孙长飞 惠节
舰船科学技术2024,Vol.46Issue(3) :75-78.DOI:10.3404/j.issn.1672-7649.2024.03.013

船用铸铁耐高温甲酸腐蚀涂层抗高温腐蚀性能研究

Research on the high-temperature corrosion resistance of formic acid corrosion resistant coatings on cast iron used in ships

刘昭亮 1孙长飞 1惠节1
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作者信息

  • 1. 江苏海事职业技术学院,江苏南京 211199
  • 折叠

摘要

为有效预防铸铁材料的腐蚀,提高船舶的安全性,研究船用铸铁耐高温甲酸腐蚀涂层抗高温腐蚀性能.制备纳米Fe粉体材料和添加了纳米Al粉和Cr3C2粉的Fe-Al/Cr3C2复合喷涂粉体材料以及指标甲酸溶液,利用正火态20钢制备铸铁试件M-1和M-2,将甲酸溶液作为腐蚀溶液,在不同高温环境下进行抗高温腐蚀性能测试.试验结果表明,铸铁涂层试件在高温甲酸溶液腐蚀后,涂层表明呈现不同程度凸起,该凸起为Al和Cr氧化物以及Fe氧化物,该氧化物对铸铁材料起到了保护膜作用,因此试件M-2的抗高温腐蚀性能较好;在相同高温甲酸溶液腐蚀环境下,试件M-2的质量损失数值也低于试件M-1,表明添加了纳米Al粉和Cr3C2粉的Fe-Al/Cr3C2复合喷涂粉体材料制备成的铸铁试件M-2抗高温腐蚀能力较强.

Abstract

In order to effectively prevent corrosion of cast iron materials and improve the safety of ships,the high-tem-perature formic acid corrosion resistance performance of cast iron coatings for ships is studied.Preparation of nano Fe powder materials and Fe Al/Cr3C2 composite spraying powder materials with the addition of nano Al powder and Cr3C2 powder,as well as indicator formic acid solution.Cast iron specimens M-1 and M-2 were prepared using normalized 20 steel,and formic acid solution was used as the corrosion solution to test their high-temperature corrosion resistance in differ-ent high-temperature environments.The experimental results show that after corrosion in high-temperature formic acid solu-tion,the cast iron coating specimen exhibits varying degrees of protrusions,which are Al and Cr oxides as well as Fe oxides.This oxide serves as a protective film for the cast iron material,so the high-temperature corrosion resistance of specimen M-2 is good;Under the same high-temperature formic acid solution corrosion environment,the mass loss value of specimen M-2 is also lower than that of specimen M-l,indicating that the cast iron specimen M-2 prepared by adding Fe-Al/Cr3C2 compos-ite spraying powder material with nano Al powder and Cr3C2 powder has strong high-temperature corrosion resistance.

关键词

船舶/铸铁/耐高温/甲酸腐蚀涂层/抗高温腐蚀性能/腐蚀速率

Key words

ship/cast iron/high temperature resistance/formic acid corrosion coating/high temperature corro-sion resistance/corrosion rate

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基金项目

江苏省高等学校基础科学(自然科学)研究面上项目(21KJB580010)

出版年

2024
舰船科学技术
中国舰船研究院,中国船舶信息中心

舰船科学技术

CSTPCD北大核心
影响因子:0.373
ISSN:1672-7649
参考文献量6
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