江汉大学学报(自然科学版)2024,Vol.52Issue(5) :5-16.DOI:10.16389/j.cnki.cn42-1737/n.2024.05.001

MgCo2O4@Co(OH)2复合材料的制备及电化学性能研究

Preparation and Electrochemical Properties of MgCo2O4@Co(OH)2 Composite Material

倪航 胡潭伟 唐梦凡 丁悦 田玉 朱小龙 郑广
江汉大学学报(自然科学版)2024,Vol.52Issue(5) :5-16.DOI:10.16389/j.cnki.cn42-1737/n.2024.05.001

MgCo2O4@Co(OH)2复合材料的制备及电化学性能研究

Preparation and Electrochemical Properties of MgCo2O4@Co(OH)2 Composite Material

倪航 1胡潭伟 1唐梦凡 1丁悦 1田玉 1朱小龙 1郑广1
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作者信息

  • 1. 江汉大学 光电化学材料与器件教育部重点实验室,湖北 武汉 430056
  • 折叠

摘要

由于复合材料具有丰富的活性位点与良好的导电性能,已成为超级电容器电极材料的研究热点之一.通过水热和电沉积法在泡沫镍上成功制备了MgCo2O4@Co(OH)2 复合材料,采用X射线衍射(XRD)、扫描电镜(SEM)以及电化学工作站对产物进行了表征和电化学性能测试.结果表明,该复合材料作为一种无粘结剂的超级电容器电极材料在电流密度为 1 mA/cm2 下的比电容高达 3 034.75 F/g;在 14 mA/cm2 的电流密度下循环 1 000圈后,比电容保持了 96%,展示出MgCo2O4 作为能量存储电极材料的巨大潜力.

Abstract

Composite materials have become one of the hot topics for supercapacitors'electrode material because of their abundant active sites and excellent electroconductivity performance.MgCo2O4@Co(OH)2 composite material was successfully synthesized on Ni foam by hydrothermal and electrodeposition in this work.The product was characterized by X-ray diffraction(XRD)and scanning electron microscopy(SEM),and the electrochemical performance of the product was tested by the electrochemical workstation.The results showed that this MgCo2O4@Co(OH)2 composite material exhibited a maximum capacitance of 3 034.75 F/g at a current density of 1 mA/cm2 when used as a binder-free electrode material for electrochemical capacitors.After 1 000 cycles at the current density of 14 mA/cm2,the specific capacitance was maintained at 96%,manifesting the great potential of MgCo2O4 as an excellent material for energy storage.

关键词

电沉积法/MgCo2O4@Co(OH)2复合材料/比电容/循环性能

Key words

electrodeposition/MgCo2O4@Co(OH)2 composite material/specific capacitance/cycle performance

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基金项目

江汉大学一流学科建设重大研究专项(2023XKZ007)

出版年

2024
江汉大学学报(自然科学版)
江汉大学

江汉大学学报(自然科学版)

影响因子:0.413
ISSN:1673-0143
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