吉林大学学报(工学版)2024,Vol.54Issue(2) :394-399.DOI:10.13229/j.cnki.jdxbgxb.20220338

碳纳米管掺杂3YSZ陶瓷的低温闪烧

Flash sintering of 3YSZ doping with CNT at low temperature

杨悦 赵培雷 马天惠 贾剑明
吉林大学学报(工学版)2024,Vol.54Issue(2) :394-399.DOI:10.13229/j.cnki.jdxbgxb.20220338

碳纳米管掺杂3YSZ陶瓷的低温闪烧

Flash sintering of 3YSZ doping with CNT at low temperature

杨悦 1赵培雷 1马天惠 1贾剑明1
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作者信息

  • 1. 长春工业大学 材料科学与工程学院,长春 130012
  • 折叠

摘要

以3 mol%氧化钇稳定氧化锆(3YSZ)粉末为基材通过添加导电相-碳纳米管(CNT),同时辅助交流电场和压力,在200℃进行复合材料的低温烧结.主要探讨了CNT含量对烧结材料的物相组成、微观组织形貌以及离子电导率的影响规律.结果表明:在此温度下材料烧结致密,相组成均为稳定相t-ZrO2;CNT含量为2%时,离子电导率为0.20 μs/cm;当CNT含量为3%时,离子电导率达到0.83 μs/cm,当CNT含量增加到4%时,材料导电性能增强,闪烧起始电压降低,但由于局部过度烧结导致离子电导率下降为 0.6 μs/cm.同时,3YSZ-4%CNT复合材料可实现室温烧结.

Abstract

In the present study,3 mol%Yttria-Stabilized Zirconia(3YSZ)powder was used as the base material doping with conductive phase-carbon nanotubes(CNT)to conduct low-temperature sintering at 200℃,and simultaneously assisting AC electric field and pressure.The effects of carbon nanotube concentration on the phase composition,microscopic morphology and ionic conductivity of sintered materials were mainly discussed.The results showed that the composites were sintered uniformly and densely at this temperature,and the ionic conductivity was 0.20 μs/cm when the concentration of carbon nanotubes was 2%;When the concentration of carbon nanotubes was 3%,the ionic conductivity 0.83 μs/cm could be reached;When the concentration of carbon nanotubes was increased to 4%,the ability of the material to withstand electric field strength and current density was further improved,and the initial voltage of flash sintering was reduced,but the conductivity was 0.6 μs/cm at this time,meantime,the material could be sintered at room temperature.

关键词

材料学/闪烧技术/碳纳米管/烧结温度/离子电导率

Key words

materials science/flash sinter/carbon nanotubes/sintering temperature/ionic conductivity

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基金项目

吉林省发改委项目(2020C029-3)

出版年

2024
吉林大学学报(工学版)
吉林大学

吉林大学学报(工学版)

CSTPCD北大核心
影响因子:0.792
ISSN:1671-5497
参考文献量11
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