首页|O2/N2和O2/CO2气氛下煤半焦-生物质的混燃特性及影响因素

O2/N2和O2/CO2气氛下煤半焦-生物质的混燃特性及影响因素

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为掌握煤半焦与生物质在O2/N2和O2/CO2条件下的混燃特性及其影响因素,采用全自动物理化学吸附仪获得了煤半焦-生物质混合燃料的孔隙结构,采用热重实验分析了两种燃料的混燃特性和反应动力学,通过多元线性回归法研究了燃料比、比表面积与混燃特性参数之间的关系.结果表明,O2/N2气氛下,掺混生物质可改善煤半焦的着火、燃尽及综合燃烧特性;O2/CO2气氛下,掺混生物质能改善煤半焦的着火特性,但会延迟其燃尽.混燃的活化能在低温区和高温区有显著差异,生物质掺混比增大,两个温区的活化能都降低;两种气氛下,低温区的活化能相近,但O2/CO2气氛下高温区的活化能显著高于O2/N2气氛下的.O2/N2气氛下孔隙结构对燃烧特性的影响更显著,而O2/CO2气氛下燃料比对燃烧特性的作用更显著.
Combustion Characteristics and Influencing Factors of Coal Semi-coke and Biomass Blends under O2/N2 and O2/CO2 Atmospheres
To understand the combustion characteristics and influencing factors of coal semi-coke and bi-omass blends under O2/N2 and O2/CO2 atmospheres,an automated physical and chemical adsorption in-strument was used to obtain the pore structure of semi-coke and biomass blends,and thermogravimetric experiments were carried out to analyze the co-combustion characteristics and reaction kinetics in this paper.In addition,multiple linear regression method was implied to investigate the relationship among the combustion characteristics parameters,fuel ratio and pore structure.The results indicated in O2/N2 atmosphere,the ignition,burnout and comprehensive combustion characteristics of coal semi-coke were improved by blending of biomass.However,in O2/CO2 atmosphere,blending of biomass can improve the ignition characteristics of semi-coke,yet delay the burnout of semi-coke.The activation energy of the blends exhibited significant differences in the low-temperature and high-temperature zones.As the blending ratio of biomass increased,the activation energies in both temperature zones gradually de-creased.The activation energies in low-temperature zone were close in the two atmospheres,while the activation energies in high-temperature zone in O2/CO2 atmosphere were observably higher than those in O2/N2 atmosphere.In O2/N2 atmosphere,the pore structure had a more significant impact on the com-bustion characteristics.While in O2/CO2 atmosphere,the fuel ratio had more notable effect on the co-combustion characteristics.

coal semi-cokebiomassco-combustionO2/CO2 atmospherepore structure

张锦萍、陈磊、沈靖淳、徐鲁橹、杜勇博、车得福

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西安交通大学 能源与动力工程学院,陕西 西安 710049

西安交通大学 化学工程与技术学院,陕西 西安 710049

煤半焦 生物质 混燃 O2/CO2气氛 孔隙结构

国家自然科学基金

52206171

2024

节能技术
国防科技工业节能技术服务中心

节能技术

CSTPCD
影响因子:0.601
ISSN:1002-6339
年,卷(期):2024.42(1)
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