金属热处理2024,Vol.49Issue(12) :122-128.DOI:10.13251/j.issn.0254-6051.2024.12.021

稀土Ce含量对S355NL低合金钢夹杂物及铸态组织与硬度的影响

Effect of Ce content on inclusions and as-cast microstructure and hardness of S355NL low alloy steel

杨建栋 谢碧君 徐斌 孙明月 李殿中
金属热处理2024,Vol.49Issue(12) :122-128.DOI:10.13251/j.issn.0254-6051.2024.12.021

稀土Ce含量对S355NL低合金钢夹杂物及铸态组织与硬度的影响

Effect of Ce content on inclusions and as-cast microstructure and hardness of S355NL low alloy steel

杨建栋 1谢碧君 2徐斌 2孙明月 2李殿中3
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作者信息

  • 1. 中国科学院金属研究所沈阳材料科学国家研究中心,辽宁沈阳 110016;大连工业大学机械工程与自动化学院,辽宁大连 116034
  • 2. 中国科学院金属研究所沈阳材料科学国家研究中心,辽宁沈阳 110016;中国科学院金属研究所中国科学院核用材料与安全评价重点实验室,辽宁沈阳 110016
  • 3. 中国科学院金属研究所沈阳材料科学国家研究中心,辽宁沈阳 110016
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摘要

在S355NL低合金钢中添加高纯稀土 Ce元素,研究不同Ce含量对高洁净度S355NL低合金钢夹杂物及铸态组织和硬度的影响.利用扫描电镜、光学显微镜和维氏硬度计对其夹杂物的类型、尺寸和形状,以及铸态组织和硬度进行测试分析.结果表明:稀土 Ce添加量为0.0011%~0.0049%时,使S355NL低合金钢中形状不规则的大尺寸Al2O3和MnS夹杂物改性为细小球状的稀土夹杂物;当添加量为0.0011%~0.0049%,稀土 Ce首先与O、S元素反应形成细小的球状稀土氧硫化物;随着稀土 Ce含量的增加,过量稀土 Ce将与As、P元素反应形成大尺寸的不规则稀土夹杂物.此外,稀土 Ce的添加可细化S355NL低合金钢的铸态枝晶,并提升S355NL低合金钢的硬度.综合考虑夹杂物改性及硬度优化,S355NL低合金钢的最佳稀土 Ce添加量为0.0011%~0.0049%.

Abstract

Effects of adding different contents high-purity rare earth Ce element on the inclusions,as-cast microstructure and hardness of high-purity S355NL low alloy steel were investigated.The types,sizes and shapes of inclusions,as well as the as-cast microstructure and hardness were analyzed and evaluated by using scanning electron microscopy,optical microscopy,and Vickers hardness testing.The results indicate that with the Ce addition ranging from 0.0011%to 0.0049%,the irregularly shaped large Al2O3 and MnS inclusions in the S355NL low alloy steel are modified into fine spherical rare earth inclusions.When Ce is added at levels between 0.0011%and 0.0049%,it initially reacts with O and S to form small spherical rare earth oxysulfides.However,with the increase of Ce content,excess Ce can react with As and P,leading to larger irregular rare earth inclusions.Additionally,the incorporation of Ce refines the dendritic structure of the S355NL low alloy steel and enhances its hardness.Considering both the inclusion modification and hardness optimization,the optimal range for Ce addition in the S355NL low alloy steel is determined to be 0.0011%to 0.0049%.

关键词

S355/NL低合金钢/稀土/Ce/夹杂物/铸态组织/硬度

Key words

S355NL low alloy steel/rare earth Ce/inclusions/as-cast microstructure/hardness

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出版年

2024
金属热处理
北京机电研究所 中国机械工程学会热处理学会 中国热处理行业协会

金属热处理

CSTPCDCSCD北大核心
影响因子:0.546
ISSN:0254-6051
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