金属热处理2024,Vol.49Issue(12) :268-273.DOI:10.13251/j.issn.0254-6051.2024.12.043

新型镍基耐热合金C-HRA-3的热力学计算

Thermodynamic calculation of a novel nickel-based heat-resistant alloy C-HRA-3

张鹏 陈正宗
金属热处理2024,Vol.49Issue(12) :268-273.DOI:10.13251/j.issn.0254-6051.2024.12.043

新型镍基耐热合金C-HRA-3的热力学计算

Thermodynamic calculation of a novel nickel-based heat-resistant alloy C-HRA-3

张鹏 1陈正宗2
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作者信息

  • 1. 东北大学材料科学与工程学院,辽宁沈阳 110819;抚顺特殊钢股份有限公司,辽宁抚顺 113001
  • 2. 钢铁研究总院有限公司,北京 100081
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摘要

通过对新型镍基耐热合金C-HRA-3中主元素含量变化进行热力学计算,对其在各温度下可能析出的第二相特征开展分析.结果表明:C-HRA-3合金中主要析出相有γ'和M23C6,其中700 ℃时γ'相的析出量约3.7wt%,M23C6相的析出量约1.11wt%.C元素对M23C6相的析出量、回溶温度以及合金的熔点有显著影响.Co元素对析出相和熔点的影响较小.Mo元素对M6C相的析出行为有决定性作用.Al和Ti含量的增加会明显增加γ'相的析出量和回溶温度.Nb元素对γ'相的析出量没有影响,但对Nb在γ'相的组成元素占比有显著影响.

Abstract

By conducting thermodynamic calculations on the changes in the content of main elements in a novel nickel-based heat-resistant alloy C-HRA-3,the possible characteristics of the second phase that might precipitate at various temperatures were analyzed.The results show that the main precipitated phases in C-HRA-3 alloy are γ'and M23C6,with a precipitation amount of approximately 3.7wt%for γ'phase and 1.11wt%for M23C6 phase at 700 ℃.The C element has a significant impact on the precipitation amount,redissolution temperature and melting point of M23C6 phase in the alloy.The effect of Co element on the precipitation phase and melting point is relatively small.The Mo element plays a decisive role in the precipitation behavior of M6C phase.The increase in Al and Ti content will significantly increase the precipitation amount and redissolution temperature of the γ'-phase.The Nb element has no effect on the precipitation amount ofγ'-phase,but has a significant impact on the proportion of Nb in the composition elements of the γ'-phase.

关键词

C-HRA-3耐热合金/热力学计算/析出相

Key words

C-HRA-3 heat-resistant alloy/thermodynamic calculation/precipitated phase

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出版年

2024
金属热处理
北京机电研究所 中国机械工程学会热处理学会 中国热处理行业协会

金属热处理

CSTPCDCSCD北大核心
影响因子:0.546
ISSN:0254-6051
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