精细化工2024,Vol.41Issue(5) :1084-1091,1160.DOI:10.13550/j.jxhg.20230474

棒状V3O7·H2O电极材料的制备及印刷超级电容器

Fabrication of rod-like V3O7·H2O electrode material and printed supercapacitor

涂倩 王婧璐 郑茵茵 林宝莹 张强 刘善培 陈良哲
精细化工2024,Vol.41Issue(5) :1084-1091,1160.DOI:10.13550/j.jxhg.20230474

棒状V3O7·H2O电极材料的制备及印刷超级电容器

Fabrication of rod-like V3O7·H2O electrode material and printed supercapacitor

涂倩 1王婧璐 1郑茵茵 1林宝莹 1张强 1刘善培 1陈良哲1
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作者信息

  • 1. 荆楚理工学院电子信息工程学院,湖北荆门 448000
  • 折叠

摘要

以V2O5为原料,利用溶剂热法一步制备了 V3O7·H2O纳米棒,采用SEM、XRD、EDS、XPS和FTIR对样品进行了测试.以V3O7·H2O纳米棒为电极材料,探究了丝网印刷工艺对电极电化学性能的影响,将此电极组装超级电容器并评价了其电化学性能.结果表明,丝网印刷电极比电容可达268.0 F/g(电流密度为0.3 A/g),经过5000次循环后电容保持率为85.9%,优于涂抹电极的比电容(246.0 F/g)和电容保持率(68.0%),这得益于丝网印刷的油墨规则排列的结构.组装的纽扣超级电容器也表现出优异的电化学性能,比电容和电容保持率为134.2 F/g(0.5 A/g电流密度)和91.2%(5000次充放电循环),且当能量密度为22.0 W·h/kg时,功率密度最高可达 4125.0 W/kg.

Abstract

V3O7·H2O nanorods were prepared via one-step solvothermal method using V2O5 as raw materials and characterized by SEM,XRD,EDS,XPS and FTIR.The influence of screen-printing technology on the electrochemical performance of electrode was investigated using V3O7·H2O nanorods as electrode material,and the electrode was further assembled into a supercapacitor and its electrochemical performance was evaluated.The results showed that the specific capacitance of the screen-printed electrode reached 268.0 F/g at a current density of 0.3 A/g,with a capacitance retention maintained at 85.9%after 5000 charge/discharge cycles,significantly improved compared with those of smeared electrode with 246.0 F/g and 68.0%,respectively.This performance improvement was attributed to the regular ink structure arrangement of screen printing.Moreover,the assembled coin supercapacitor exhibited excellent electrochemical performance with a specific capacitance of 134.2 F/g at 0.5 A/g and capacitance retention of 91.2%after 5000 charge/discharge cycles.And the power density reached as high as 4125.0 W/kg when the energy density was 22.0 W·h/kg.

关键词

七氧化三钒/纳米棒/丝网印刷/纽扣超级电容器/有机电化学

Key words

V3O7·H2O/nanorods/screen-printing/coin supercapacitor/electro-organic chemistry

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基金项目

湖北省高等学校优秀中青年科技创新团队项目(T2022038)

荆门市重点科技计划(2022YFZD045)

荆门市重点科技计划(2020YFZD007)

大学生创新创业训练计划(S202311336001)

出版年

2024
精细化工
大连化工研究院设计院 中国化工学会精细化工专业委员会 辽宁省化工研究院

精细化工

CSTPCDCSCD北大核心
影响因子:0.557
ISSN:1003-5214
参考文献量47
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