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油气田刺激响应性材料应用现状及前景展望

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油田化学品在钻井完井、压裂酸化、调剖堵水、乳化降黏、油水分离等环节发挥关键作用,但低渗透、高温、高盐、极端pH及使用过程中温度、pH变化等苛刻油气藏环境,给应用于油田化学品的聚合物和表面活性剂的研发带来了严峻的挑战.引入磺酸基等抗温抗盐基团或增大驱油剂相对分子质量等传统方式已难以满足油田需求.该文介绍了温度敏感聚合物、pH敏感聚合物、磁响应聚合物、CO2敏感聚合物及表面活性剂、盐度敏感聚合物响应环境变化的刺激响应原理和性能;综述了 5 种刺激响应性材料在钻井完井、提高采收率、乳化破乳、压裂酸化、调剖堵水、油水分离等方向的应用,展望了刺激响应性材料在油气开采中的发展前景.
Application status and prospects of stimuli-responsive materials in oil and gas fields
Oilfield chemicals play a crucial role in drilling and completion,fracturing and acidizing,profile control and water plugging,emulsification and viscosity reduction,oil-water separation,etc.However,the harsh oil reservoir environment such as low permeability,high temperature,high salinity,extreme pH,and changes in temperature or pH has brought severe challenges to the research of polymers and surfactants used in oilfield chemicals.The traditional methods of introducing sulfonic groups to achieve temperature-resistant or salinity-resistant and increasing the relative molecular mass of oil displacement agents can no longer meet the oilfield needs.In this review,the principle and properties of temperature-sensitive polymers,pH-sensitive polymers,magnetic-responsive polymers,CO2-sensitive polymers and surfactants,and saline-sensitive polymers in response to environmental changes were introduced.The application of 5 types stimuli-responsive materials in drilling and completion,enhanced oil recovery,emulsification and demulsification,fracturing and acidizing,profile control and water plugging,oil-water separation and so on were summarized.Finally,the development prospect of stimuli-responsive materials in oil and gas production was discussed.

stimuli-responsive materialsoil and gas productiontemperature-sensitivepH-sensitivemagnetic-responsiveCO2-sensitivesalinity-sensitive

谢坤、程前、刘长龙、曹杰、殷庆国、何佳伟、曹伟佳

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东北石油大学 提高油气采收率教育部重点实验室,黑龙江 大庆 163318

中海石油(中国)有限公司天津分公司渤海石油研究院,天津 300459

中国石油大学(华东)石油工程学院,山东 青岛 266580

大港油田公司石油工程研究院,天津 300280

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刺激响应材料 油气开采 温度敏感 pH敏感 磁响应 CO2敏感 盐度敏感

国家自然科学基金项目国家自然科学基金项目黑龙江省重点研发计划项目2021年度中央支持地方高校改革发展基金优秀青年人才项目

52204037U19B2011JD22A004

2024

精细化工
大连化工研究院设计院 中国化工学会精细化工专业委员会 辽宁省化工研究院

精细化工

CSTPCD北大核心
影响因子:0.557
ISSN:1003-5214
年,卷(期):2024.41(7)