首页|类水黾脚部"凹凸沟壑"结构仿生超疏水涂层的制备与性能

类水黾脚部"凹凸沟壑"结构仿生超疏水涂层的制备与性能

扫码查看
以坡缕石粉为功能颜料,环氧树脂 E-44 和杜仲胶混合物为成膜物质,在涂有环氧/杜仲胶清漆的表面制备了一层具有类水黾脚部"凹凸沟壑"结构的仿生超疏水涂层.对涂层进行了SEM、FTIR、XRD表征,对C3涂层(坡缕石粉质量分数为 25%)进行了水接触角、水滚动角、自清洁性能、抗润湿性能、耐磨性能、耐水性能测试.结果表明,C3涂层表面具有明显的"凹凸沟壑"结构,其静态、动态水接触角分别为153.1°、152.6°,水滚动角为 8.8°,具有优异的自清洁性能;C3 涂层对泥土浆液、甲基橙溶液和亚甲基蓝溶液具有优良的抗润湿性,接触角均>150°;C3涂层具有良好的基材适用性,涂覆于混凝土、织物棉布、纸张及塑料表面均具有超疏水性能;经过载重为100 g的A4纸循环打磨50次,C3涂层水接触角仍高达151.9°,具有较好的耐磨性能;C3涂层在经过18和24 h浸泡后,其水接触角分别为152.2°和144.4°.
Preparation and properties of bionic superhydrophobic coating with"concave and convex gully"structure like foot of water strider
A bionic superhydrophobic coating with"concave and convex gully"structure,which is like foot of water strider,was developed on the epoxy/gutta-percha varnish surface using palygorskite powder as functional pigment and mixture of epoxy resin E-44 and gutta-percha as film-forming material,and characterized by SEM,FTIR,XRD.The C3 coating,prepared with 25%(mass fraction)of palygorskite powder was then evaluated for its water contact angle,water rolling angle,self-cleaning capacity,wettability,wear resistance and water resistance.The results showed that the C3 coating displayed obvious"concave and convex gully"structure,with the average static and dynamic water contact angle of 153.1° and 152.6°,respectively,the water rolling angle of 8.8°,and excellent self-cleaning performance.Meanwhile,the C3 coating showed excellent wettability resistance to mud slurry,methyl orange solution and methylene blue solution,with all contact angles above 150°.Moreover,the C3 coating exhibited good substrate applicability,and super hydrophobic properties on the surface of concrete,fabric,paper and plastic.After 50 times of cyclic polishing with 100 g A4 paper,the coating still retained a water contact angle as high as 151.9°,showing good wear resistance.After soaked for 18 and 24 h,the C3 coating displayed water contact angle of 152.2° and 144.4°,respectively.

bionic superhydrophobic coating"concave and convex gully"structurepalygorskite powdergutta-perchafunctional materials

陈健君、易帆、邱培华、陈加漓、罗嘉晋、邱桃杰、孟琨明、雷辉斌

展开 >

吉首大学 化学化工学院,湖南 吉首 416000

吉首大学 矿物清洁生产与绿色功能材料开发湖南省重点实验室,湖南 吉首 416000

仿生超疏水涂层 "凹凸沟壑"结构 坡缕石粉 杜仲胶 功能材料

国家级重点大学生创新训练项目湖南省自然科学基金青年项目教育厅青年项目湖南省创新省份建设专项

2022105310012023JJ4051622B05512020SK2028

2024

精细化工
大连化工研究院设计院 中国化工学会精细化工专业委员会 辽宁省化工研究院

精细化工

CSTPCD北大核心
影响因子:0.557
ISSN:1003-5214
年,卷(期):2024.41(7)